ARCHIVE

Aviation materials and technologies №4, 2014

Contents

  • D.K. Ryabov, N.I. Kolobnev, A.Ya. Kochubey, A.V. Zavodov

    Сhanging of mechanical properties of 1913 alloy sheets after scandium addition

    3-8
  • S.A. Karimova, A.E. Kutyrev, T.G. Pavlovskaya, K.E. Zakharov

    Low temperature sealing of anodic oxide coatings on parts of aluminum alloys

    9-17
  • M.A. Fomina, S.A. Karimova

    Study of corrosion properties of V-1461-T1 aluminum alloy sheets in all-climatic conditions of aerotechnics operation

    18-22
  • A.A. Shiryaev, V.G. Antashev

    Peculiarities of development of advanced high-strength self-hardening high-processable pseudo-β-titanium alloys

    23-30
  • A.B. Echin, Yu.A. Bondarenko

    New industrial high-gradient UVNS-6 unit for manufacture of GTE blades and other parts from casting heat-resistant and intermetallic alloys with single-crystal structure

    31-36
  • V.A. Ilyin, A.V. Panarin

    Aluminum coatings and methods of their manufacture

    37-42
  • A.A. Platonov

    Polymer composite materials on a base of stitched preforms with high impact resistance

    43-47
  • A.V. Borshchev, Y.A. Gusev

    Development and implementation of PCM in automotive industry. Varieties of HP-RTM processes

    48-52
  • R.R. Mukhametov, E.V. Dolgova, Yu.I. Merkulova, M.I. Dushin

    Development of heat-resistant bismaleimide binder for composites of aeronautical applications

    53-57
  • G.N. Petrova, E.Ya. Beyder

    Increasing of fire resistance of polybutylene terephthalate (review)

    58-64
  • I.V. Parakhin, A.S. Tumanov

    Phenolic-rubber foamed plastic of higher plasticity

    65-67
Содержание номера
1.

DOI: 10.18577/2071-9140-2014-0-4-3-8

UDC: 669.715

Pages:: 3-8

D.K. Ryabov1, N.I. Kolobnev2, A.Ya. Kochubey3, A.V. Zavodov1

[1] Federal state unitary enterprise «All-Russian Scientific-Research Institute of Aviation Materials» of National Research Center «Kurchatov Institute»
[2] Federal state unitary enterprise «All-Russian Scientific-Research Institute of Aviation Materials» of National Research Center «Kurchatov Institute», admin@viam.ru
[3] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru

Сhanging of mechanical properties of 1913 alloy sheets after scandium addition

Al-Zn-Mg alloys are widely used as structural materials for a large number of applications including automotive industry, building, and aeronautical engineering. Scandium is a rare-earth metal, which modifies a structure of semi-products because of affecting on recrystallization processes. Sc addition in alloys leads to increasing of ultimate tensile and yield strength because of Al 3Sc intermetallides formation of nanoscale size. This paper describes the results of influence of small addition of scandium (not less than 0,1% wt.) on mechanical properties of cold-rolled sheets of 1913 alloy. It is a medium strength corrosion resistant weldable Al-Zn-Mg alloy with addition of Cu for improvement of stress corrosion resistance. It is shown that addition of Sc transforms a kinetics of artificial aging and accelerates a decomposition of oversaturated solid solution, and allows also to increase an ultimate tensile strength by 50 MPa in artificially aged temper. Results of mechanical tests including fracture toughness and low cycle fatigue tests are introduced.

Keywords: 1913 alloy, scandium, heat treatment, texture, recrystallization

Reference List

    1. Kablov E.N. Strategicheskie napravlenija razvitija materialov i tehnologij ih pererabotki na period do 2030 goda [Strategic directions of development of materials and technologies of their processing for the period up to 2030] //Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
    2. Antipov V.V., Senatorova O.G., Tkachenko E.A., Vahromov R.O. Aljuminievye deformiruemye splavy [Wrought aluminum alloys] //Aviacionnye materialy i tehnologii. 2012. №S. S. 167–182.
    3. Fridljander I.N., Chuistov K.V., Berezina A.L. i dr. Aljuminij-litievye splavy. Struktura i svojstva [Aluminum-lithium alloys. Structure and Properties]. Kiev: Naukova dumka. 1992.
    4. Aljuminievye splavy [Aluminium alloys] /V kn. Istorija aviacionnogo materialovedenija. VIAM – 80 let: gody i ljudi. Pod obshh. red. E.N. Kablova. M.: VIAM. 2012. S. 143–156.
    5. Kablov E.N. Aviakosmicheskoe materialovedenie [Aerospace Materials Engineering] //Vse materialy. Jenciklopedicheskij spravochnik. 2008. № 3. S. 2–14.
    6. Alieva S.G., Al'tman M.B., Ambarcumjan S.M. i dr. Promyshlennye aljuminievye splavy [Industrial aluminum alloys]: Spravochnik. M.: Metallurgija. 1984. 527 s.
    7. Elagin V.I. Legirovanie deformirovannyh aljuminievyh splavov perehodnymi metallami [Doping of deformed aluminum transition metal alloys]. M.: Metallurgija. 1975. 321 s.
    8. Elagin V.I., Zaharov V.V., Dric A.M. Struktura i svojstva splavov sistemy Al–Zn–Mg [The structure and properties of alloys of Al-Zn-Mg]. M.: Metallurgija 1982. 222 s.
    9. Mukhopadhyay A.K., Prasad K.S., Vikas Kumar et al. Key Microstructural Features Responsible for Improved Stress Corrosion Cracking Resistance and Weldability in 7xxx Series Al Alloys Containing Micro/Trace Alloying Additions /Proceedings of the 10-th International Conference on Aluminium Alloys. Vancouver. 2006. Р. 315–320.
    10. Ying Deng, Zhimin Yin, Kai Zhao et al. Effects of Sc and Zr microalloying additions and aging time at 120°С on the corrosion behaviour of an Al–Zn–Mg alloy //Corrosion Science. 2012. V. 65. Р. 288–298.
    11. Marlauda T., Deschampsa A., Bleya F., et al. Influence of alloy composition and heat treatment on precipitate composition in Al–Zn–Mg–Cu alloys //Acta Materialia. 2010. V. 58. №1. P. 248–260.
    12. Liang Zou, Qing-lin Pan, Yun-bin He, Chang-Zhen Wang. Effect of minor Sc and Zr addition on microstructures and mechanical properties of Al–Zn–Mg–Cu alloys //Transactions of Nonferrous Metals Society of China. 2006. №10. P. 340–344.
    13. Liang Zou, Qing-Lin Pan, Yun-Bin He et al. Microstructures and tensile properties of Al–Zn–Cu–Mg–Zr alloys modified with scandium //Materials Science. 2008. №44. P. 120–125.
    14. Kablov E.N. Sovremennye materialy – osnova innovacionnoj modernizacii Rossii [Modern materials – the basis of innovative modernization of Russia] //Metally Evrazii. 2012. №3. S. 10–15.
    15. Grigor'ev M.V., Antipov V.V., Vahromov R.O. i dr. Struktura i svojstva slitkov iz splava sistemy Al–Cu–Mg s mikrodobavkami serebra [The structure and properties of the alloy ingot of
    Al–Cu–Mg with micro silver] //Aviacionnye materialy i tehnologii. 2013. №3. S. 3–6.
    16. Rjabov D.K., Kolobnev N.I., Mahsidov V.V., Fomina M.A. O stabil'nosti peresyshhennogo tverdogo rastvora listov splava 1913 pri zakalke [On the stability of the supersaturated solid solution alloy sheets 1913 during quenching] //Metallurgija mashinostroenija. 2012. №3. S. 30–33.
    17. Loshhinin Ju.V., Pahomkin S.I., Fokin A.S. Vlijanie skorosti nagrevanija pri issledovanii fazovyh prevrashhenij v aljuminievyh splavah metodom DSK [Effect of heating rate in the study of phase transformations in aluminum alloys by DSC] //Aviacionnye materialy i tehnologii. 2011. №2. S. 3–6.
    18. Rohlin L.L., Dobatkina T.V., Korol'kova I.G., Bolotova M.N. Issledovanie sovmestnogo vlijanija skandija i hroma na strukturu i mehanicheskie svojstva aljuminija i ego splavov s magniem [study of joint influence of scandium and chromium on the structure and mechanical properties of aluminum and its alloys with magnesium] //Materialovedenie i termicheskaja obrabotka. 2008. №3. S. 115–119.
    19. Rjabov D.K., Kolobnev N.I. Izmenenie mehanicheskih svojstv splava 1913 pri dvuhstu-penchatom iskusstvennom starenii [Changes in mechanical properties of alloy 1913 with a two-stage artificial aging] //Aviacionnye materialy i tehnologii. 2013. №4. S. 3–7.
    20. Rjabov D.K., Kolobnev N.I., Samohvalov S.V., Vahromov O.V. Izmenenie mehanicheskih i korrozionnyh svojstv splava 1913 pri iskusstvennom starenii [Changing the mechanical and corrosion properties of alloy 1913 in the artificial aging] //Voprosy materialovedenija. 2013. №4 (76). C. 24–29.
    21. Rjabov D.K., Kolobnev N.I., Samohvalov S.V., Mahsidov V.V. Vlijanie predvaritel'nogo estestvennogo starenija na svojstva splava 1913 v iskusstvenno sostarennom sostojanii [Effect of prior natural aging on the properties of alloy 1913 in the artificially aged condition] //Aviacionnye materialy i tehnologii. 2013. №2. S. 8–11.

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2.

DOI: 10.18577/2071-9140-2014-0-4-9-17

UDC: 629.7.023

Pages:: 9-17

S.A. Karimova1, A.E. Kutyrev2, T.G. Pavlovskaya3, K.E. Zakharov2

[1] Federal state unitary enterprise «All-Russian Scientific-Research Institute of Aviation Materials» of National Research Center «Kurchatov Institute» State research center of the Russian Federation, admin@viam.ru
[2] Federal state unitary enterprise «All-Russian Scientific-Research Institute of Aviation Materials» of National Research Center «Kurchatov Institute»
[3] Federal state unitary enterprise «All-Russian Scientific-Research Institute of Aviation Materials» of National Research Center «Kurchatov Institute», admin@viam.ru

Low temperature sealing of anodic oxide coatings on parts of aluminum alloys

A seal technology of protective non-metallic inorganic sulfuric acid anodic-oxide coatings of aluminum and aluminum-lithium alloys at low temperature in solutions containing aluminum corrosion inhibitors with improved environmental characteristics was studied. A mixture of the solution, allowing to decrease a typical seal temperature more, than 2 times was developed. To determine protective characteristics of the sealed against this technology coating in addition to the standard methods (test «drop by drop», corrosion spray tests in SFC) electrochemical methods of anode polarization and impedance spectroscopy were used.

Keywords: anode oxidation, anodic-oxide coatings, sealing, inhibitors, aluminum and aluminum-lithium alloys

Reference List

        1. Kablov E.N. Strategicheskie napravlenija razvitija materialov i tehnologij ih pererabotki na period do 2030 goda [Strategic directions of development of materials and technologies of their processing for the period up to 2030] //Aviacionnye materialy i tehnologii. 2012. №S. C. 7–17.
    2. Kablov E.N. Korrozija ili zhizn' [Corrosion or life] //Nauka i zhizn'. 2012. №11. S. 17–21.
    3. Kablov E.N. Aviakosmicheskoe materialovedenie [Aerospace Materials Engineering] //Vse materialy. Jenciklopedicheskij spravochnik. 2008. №3. S. 2–14.
    4. Karimova S.A., Pavlovskaja T.G. Razrabotka sposobov zashhity ot korrozii konstrukcij, rabotajushhih v uslovijah kosmosa [Development of methods of corrosion protection structures operating in space] //Trudy VIAM. 2013. №4. St. 02 (viam-works.ru).
    5. Shrejder A.V. Oksidirovanie aljuminija i ego splavov [Oxidation of aluminum and its alloys]. M.: Metallurgizdat. 1960. 220 s.
    6. Vernik S. Himicheskaja i jelektrohimicheskaja obrabotka aljuminija i ego splavov [Chemical and electrochemical machining of aluminum and its alloys]: Per. s angl. M.: Sudpromizdat. 1960. 218 s.
    7. Shherbakov A.I., Oshe E.K., Skvorcova I.V. i dr. Formirovanie nanoporistyh anodno-oksidnyh plenok na chistom aljuminii v vode [Formation of nanoporous anodic oxide film on pure aluminum in water] //Fizikohimija poverhnosti i zashhita materialov. 2014. №2. S. 176–180.
    8. Aver'janov E.E. Spravochnik po anodirovaniju [Handbook of anodization]. M.: Mashinostroenie. 1988. 132 s.
    9. Tomashov N.D., Tjukina M.N., Zalivalov F.P. Tolstoslojnoe anodirovanie aljuminija i ego splavov [Thick Anodizing of aluminum and its alloys]. M.: Mashinostroenie. 1968. 156 s.
    10. Sivokon' I.S. Material'nyj balans raspredelenija ingibitorov korrozii pri laboratornom testirovanii i promyshlennom primenenii [Material balance the distribution of corrosion inhibitors in laboratory testing and industrial applications] //Korrozija: materialy, zashhita. 2013. №6. S. 8–18.
    11. Tkalenko D.A., Venkatesvaran G., Vishnevskaja Ju.P. i dr. Ingibirujushhee dejstvie cisteina v kislyh sredah [Inhibitory effect of cysteine under acidic conditions] //Fizikohimija poverhnosti i zashhita materialov. 2010. №5. S. 537.
    12. Mansfeld F. Use of electrochemical impedance spectroscopy for the study of corrosion protection by polymer coating //Journal of Applied Electrochemistry. 1995. V. 25. P. 187–202.
    13. Liu X., Xiong J., Lv Y., Zuo Y. Study on corrosion electrochemical behavior of several different coating systems by EIS //Progress in Organic Coatings. 2009. V. 64. №4. P. 497–503.
    14. Bordziłowski J., Królikowska A., Bonora P.L. et al. Underwater EIS measurements //Progress in organic coatings. 2010. V. 67. №4. Р. 414–419.
    15. Golubev A.I. Anodnoe okislenie aljuminievyh splavov [Anodic oxidation of aluminum alloys]. M.: AN SSSR. 1961. 199 s.
    16. Antipov V.V., Senatorova O.G., Tkachenko E.A., Vahromov R.O. Aljuminievye deformiruemye splavy [Wrought aluminum alloys] //Aviacionnye materialy i tehnologii. 2012. №S. C. 167–182.
    17. Fridljander I.N., Chuistov K.V., Berezina A.L. i dr. Aljuminij-litievye splavy. Struktura i svojstva [Aluminum-lithium alloys. Structure and Properties]. Kiev: Naukova dumka. 1992.
    18. Antipov V.V., Kolobnev N.I., Hohlatova L.B. Razvitie aljuminijlitievyh splavov i mnogostupenchatyh rezhimov termicheskoj obrabotki [Development alyuminiylitievyh alloys and multistage heat treatment] //Aviacionnye materialy i tehnologii. 2012. №S. S. 183–195.
    19. Zhilikov V.P., Karimova S.A., Leshko S.S., Chesnokov D.V. Issledovanie dinamiki korrozii aljuminievyh splavov pri ispytanii v kamere solevogo tumana (KST) [Investigation of the dynamics of corrosion of aluminum alloys when tested in the salt spray chamber (KST)] //Aviacionnye materialy i tehnologii. 2012. №4. S. 18–22.
    20. Hohlatova L.B., Kolobnev N.I., Antipov V.V. i dr. Vlijanie korrozionnoj sredy na skorost' rosta treshhiny ustalosti v aljuminievyh splavah [Effect of the corrosive environment on the rate of growth of fatigue cracks in the aluminum alloys] //Trudy VIAM. 2013. №3. St. 05 (viam-works.ru).
    21. Rastvor dlja uplotnenija anodno-oksidnogo pokrytija aljuminievyh splavov [The solution is to seal the anodic oxide coating of aluminum alloys]: pat. 2447201 Ros. Federacija; opubl. 10.04.2012.
    22. Tran A.T., Huet F., Ngo K., Rousseau P. Artefacts in electrochemical impedance measurement in electrolytic solutions due to the reference electrode //Electrochimica Acta.  2011. V. 56. №23. P. 8034–8039.
    23. Wen L., Wang Y., Zhou Y. et al. Corrosion evaluation of microarc oxidation coatings formed on 2024 aluminium alloy //Corrosion Science. 2010. V. 52. №8. P. 2687–2696.
    24. Karimova S.A., Pavlovskaja T.G., Petrova A.P. Podgotovka poverhnosti aljuminievyh spla-vov s primeneniem anodnogo oksidirovanija [Surface preparation of aluminum alloys using anodic oxidation] //Klei. Germetiki. Tehnologii. 2014. №4. S. 34–38.
    25. Semenova L.V., Malova N.E., Kuznecova V.A., Pozhoga A.A. Lakokrasochnye materialy i pokrytija [Coating materials and coating] //Aviacionnye materialy i tehnologii. 2012. №S.
    S. 315–327.

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3.

DOI: 10.18577/2071-9140-2014-0-4-18-22

UDC: 669.715:620.193

Pages:: 18-22

M.A. Fomina1, S.A. Karimova2

[1] Federal state unitary enterprise «All-Russian Scientific-Research Institute of Aviation Materials» of National Research Center «Kurchatov Institute»
[2] Federal state unitary enterprise «All-Russian Scientific-Research Institute of Aviation Materials» of National Research Center «Kurchatov Institute» State research center of the Russian Federation, admin@viam.ru

Study of corrosion properties of V-1461-T1 aluminum alloy sheets in all-climatic conditions of aerotechnics operation

A corrosion behavior of high-strength weldable V-1461 aluminum-lithium alloy of Al-Cu-Li-Zn system was investigated at rapid laboratory and field corrosion tests under conditions of moderate warm climate of seaside atmosphere; standardized test methods for a tendency to the most dangerous types of corrosion damages (intercrystalline, exfoliation corrosion, corrosion cracking) were used. Influence of aging modes on corrosion resistance of V-1461 sheets including under the impact of operational heatings was investigated.

Keywords: corrosion behavior, aluminum-lithium alloys, test methods, corrosion damages

Reference List

        1. Kablov E.N. Strategicheskie napravlenija razvitija materialov i tehnologij ih pererabotki na period do 2030 goda [Strategic directions of development of materials and technologies to process them for the period up to 2030] //Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
    2. Fridljander I.N., Chuistov K.V., Berezina A.L. i dr. Aljuminij-litievye splavy. Struktura i svojstva [Aluminum-lithium alloys. Structure and Properties]. Kiev: Naukova dumka. 1992.
    3. Semenova I.V., Florianovich G.M., Horoshilov A.V. Korrozija i zashhita ot korrozii [Corrosion and Corrosion Protection]. M.: Fizmatlit. 2002. 336 s.
    4. Kablov E.N. Korrozija ili zhizn' [Corrosion or life] //Nauka i zhizn'. 2012. №11. S. 16–21.
    5. Kablov E.N., Karimova S.A., Semenova L.V. Korrozionnaja aktivnost' ugleplastikov i zashhita metallicheskih silovyh konstrukcij v kontakte s ugleplastikom [Corrosiveness CFRP and protection of metal bearing structures in contact with CFRP] //Korrozija: materialy i zashhita. 2011. №12. S. 1–7.
    6. Karimova S.A., Zhilikov V.P., Mihajlov A.A. Naturno-uskorennye ispytanija aljuminievyh splavov v uslovijah vozdejstvija morskoj atmosfery [Natural-accelerated testing of aluminum alloys under the action of the marine atmosphere] //Korrozija: materialy i zashhita. 2012. №10. S. 1–3.
    7. Hohlatova L.B., Kolobnev N.I., Antipov V.V. i dr. Vlijanie korrozionnoj sredy na skorost' rosta treshhiny ustalosti v aljuminievyh splavah [Effect of environment on corrosion fatigue crack growth rate in aluminum alloys] //Aviacionnye materialy i tehnologii. 2011. №1. S. 16–20.
    8. Zhilikov V.P., Karimova S.A., Leshko S.S., Chesnokov D.V. Issledovanie dinamiki korrozii aljuminievyh splavov pri ispytanii v kamere solevogo tumana (KST) [Study of the dynamics of corrosion of aluminum alloys when tested in the salt spray chamber (SSC)] //Aviacionnye materialy i tehnologii. 2012. №4. S. 18–22.
    9. Zhirnov A.D., Strekalov P.V., Karimova S.A., Zhilikov V.P. Sezonnaja dinamika processa korrozii metallov na beregovoj zone Chernogo morja [Seasonal dynamics of corrosion of metals on the coastal zone of the Black Sea] //Korrozija: materialy i zashhita. 2007. №8. S. 23–29.
    10. Antipov V.V., Senatorova O.G., Tkachenko E.A., Vahromov R.O. Aljuminievye deformiruemye splavy [Aluminium wrought alloys] //Aviacionnye materialy i tehnologii. 2012. №S. S. 167–182.
    11. Antipov V.V., Kolobnev N.I., Hohlatova L.B. Razvitie aljuminijlitievyh splavov i mnogostupenchatyh rezhimov termicheskoj obrabotki [Development alyuminiylitievyh al-loys and multi-heat treatment] //Aviacionnye materialy i tehnologii. 2012. №S. S. 183–195.
    12. Akimov G.V. Teorija i metody issledovanija korrozii metallov [Theory and Methods of metal corrosion]. M.: Izd-vo AN SSSR. 1945. 350 s.
    13. Hohlatova L.B., Oglodkov M.S., Ponomarev E.K. Vlijanie rezhimov starenija na korrozionnuju stojkost' listov iz splava V-1461 sistemy Al–Li–Cu–Zn–Mg [Effect of aging on the corrosion resistance of the alloy in sheet-1461 system Al–Li–Cu–Zn–Mg] //Metallurgija mashinostroenija. 2012. №3. S. 22–26.
    14. Hohlatova L.B., Kolobnev N.I., Oglodkov M.S. i dr. Izmenenie fazovogo sostava v zavisimosti ot rezhimov starenija i struktury polufabrikatov splava V-1461 [Phase composition change depending on the mode of aging structures and semi-finished alloy V-1461] //MiTOM. 2012. №6. S. 20–24.
    15. Oglodkov M.S., Hohlatova L.B., Kolobnev N.I. i dr. Vlijanie termomehanicheskoj obrabotki na svojstva i strukturu splava sistemy Al–Cu–Mg–Li–Zn [Effect of thermomechanical treatment on the properties and structure of the alloy of Al–Cu–Mg–Li–Zn] //Aviacionnye materialy i tehnologii. 2010. №4. S. 7–11.
    16. Fridljander I.N., Grushko O.E., Antipov V.V. i dr. Aljuminijlitievye splavy [Alyuminiylitievye alloys] /V kn. 75 let. Aviacionnye materialy. Izbrannye trudy «VIAM» 1932–2007. Jubilejnyj nauch.-tehn. sb. M.: VIAM. 2007. S. 163–171.
    17. Moran J.P., Bovard F.S., Chrzan J.D. et al. Improvements in Corrosion Resistance Offered By Newer Generation 2x99 Aluminum-Lithium Alloys for Aerospace Applications /In.: Proceedings of the 12-th International Conference on Aluminium Alloys. Yokohama. 2010. R. 1492–1497.

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4.

DOI: 10.18577/2071-9140-2014-0-4-23-30

UDC: 669.295

Pages:: 23-30

A.A. Shiryaev1, V.G. Antashev2

[1] Federal state unitary enterprise «All-Russian Scientific-Research Institute of Aviation Materials» of National Research Center «Kurchatov Institute»
[2] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru

Peculiarities of development of advanced high-strength self-hardening high-processable pseudo-β-titanium alloys

The role and place of pseudo-β-alloys in development of modern structural titanium alloys have been shown; a complex of physical- mechanical and technological characteristics of pseudo-β-alloys has been analyzed. The prospects of new advanced alloys development have been revealed for the present type of alloys. Optimal alloying limits have also been determined. A matrix of chemical composition has been chosen for the new high-strength and high-processable self-hardening pseudo-β-titanium alloy development.

Keywords: pseudo-β-titanium alloys, high-strength titanium alloys, workability, chemical composi-tion, properties

Reference List

    1. Bratuhin A.G., Kolachev B.A., Sadkov V.V. i dr. Tehnologija proizvodstva titanovyh samoletnyh konstrukcij [Technology of production of titanium aircraft structures]. M.: Mashinostroenie. 1995. 448 s.
    2. Kablov E.N. Aviakosmicheskoe materialovedenie [Aerospace Materials Engineering] //Vse materialy. Jenciklopedicheskij spravochnik. 2008. № 3. S. 2–14.
    3. Kablov E.N. Strategicheskie napravlenija razvitija materialov i tehnologij ih pererabotki na period do 2030 goda [Strategic directions of development of materials and technologies of their processing for the period up to 2030] //Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
    4. Glazunov S.G., Moiseev V.N. Titanovye splavy. Konstrukcionnye titanovye splavy [Titanium alloys. Structural titanium alloys]. M.: Metallurgija. 1974. 368 s.
    5. Moiseev V.N. Beta-titanovye splavy i perspektivy ih razvitija [Beta-titanium alloys and their development prospects] //MiTOM. 1998. №12. S. 11–14.
    6. Materials properties handbook: titanium alloys /Ed. by R. Boyer, G. Welsch, E.W. Collings. ASM International. The Material Information Society. 1994. 1176 p.
    7. Horev A.I., Belov S.P., Glazunov S.G. Metallovedenie titana i ego splavov [Metallography of titanium and its alloys]. M.: Metallurgija. 1992. 352 s.
    8. Il'in A.A., Kolachev B.A., Pol'kin I.S. Titanovye splavy. Sostav, struktura, svojstva [Titanium alloys. The composition, structure and properties]: Spravochnik. M.: VILS–MATI. 2009. 520 s.
    9. Shirjaev A.A., Nochovnaja N.A., Antashev V.G., Alekseev E.B. Perspektivy i osobennosti primenenija sovremennyh jekonomnolegirovannyh vysokoprochnyh titanovyh splavov [Prospects and especially the use of modern high-strength titanium alloys ehkonomnolegirovannyh] //Tehnologija legkih splavov. 2013. №2. S. 29–35.
    10. El-Dhaikh Ali, Schmidt Peter, Christ Hans J. Study on Beneficial Effects of Duplex Aging on Microstructure Phenomena Determining the Fatigue life of the Metastable β-titanium Alloy Ti 38-644 /Proceedings of the 12-th World Conference on Titanium «Ti–2011 Science and Technology». Beijing: Science press. 2012. V. 1. P. 745–749.
    11. Aeby-Gautier Elisabeth, Denand Benoit, Teixeira Julien et al. Influence of Microstructure on tensile Properties of β-metastable Ti 17 Alloy /Proceedings of the 12-th World Conference on Titanium «Ti–2011 Science and Technology». Beijing: Science press. 2012. V. 2. P. 1191–1195.
    12. Markovsky Pavlo E., Ikeda Masahiko. Balancing of Mechanical Properties of Ti–4.5Fe–7.2Cr–3.0Al Using Thermomechanical Processing and Rapid Heat Treatment //Materials Transactions. 2005. V. 46. №7. P. 1515–1524.
    13. Bania P.J., Hutt A.J., Adams R.E. Ultra high strength titanium alloy for fasteners /Proceedings of the 7-th World Conference on Titanium «Ti–92 Science and Technology». 1993.
    P. 2899–2906.
    14. Allen P.G., Bania P.J., Hutt A.J., Combres Y. Timetal LCB: A low cost beta alloy for automotive and other industrial applications /Proceedings of the 8-th World Conference on Titanium «Ti–1995 Science and Technology». London: The Institute of Materials. 1996. V. 1.
    P. 1680–1684.
    15. Titanium and titanium alloys. Fundamentals and applications /Ed. by Leyens C., Peters M. Wiley–VCH, Germany. 2003. 513 p.
    16. Jackson M., Dashwood R.J., Christodoulou L., Flower H.M. Wiredrawing of low cost beta titanium (Timetal LCB) /Proceedings of the 10-th World Conference on Titanium «Ti–2003 Science and Technology». Weinheim: WILEY-VCH. 2004. V. 1. P. 357.
    17. Yang Zhijun, Kou Hongchao, Zhang Fengshou et al. The Effect of VAR Process Parameters on Beta Flecks Formation in Ti–10V–2Fe–3Al /Proceedings of the 12-th World Conference on Titanium «Ti–2011 Science and Technology». Beijing: Science press. 2012. V. 1. P. 601–604.
    18. Sposob termicheskoj obrabotki vysokoprochnyh (α+β)-titanovyh splavov [A method of heat treatment of high (α+β) alloy titanic]: pat. 2465366 Ros. Federacija; opubl. 15.09.2011.
    19. Jakovlev A.L., Nochovnaja N.A. Vlijanie termicheskoj obrabotki na svojstva listov iz vysokoprochnogo titanovogo splava VT23M [Effect of heat treatment on the properties of sheets of high strength titanium alloy VT23M] //Aviacionnye materialy i tehnologii. 2013. №4. S. 8–13.
    20. Nochovnaja N.A., Skvorcova S.V., Anishhuk D.S. i dr. Otrabotka tehnologii opytnogo zharoprochnogo splava na osnove intermetallida Ti2AlNb [Technology development experienced superalloy based intermetallic Ti2AlNb] //Titan. 2013. №4. S. 24–29.
    21. Kablov E.N., Ospennikova O.G., Vershkov A.V. Redkie metally i redkozemel'nye jelementy – materialy sovremennyh i budushhih vysokih tehnologij [Rare metals and rare earth elements - materials of current and future high-tech] //Trudy VIAM. 2013. №2. St. 01 (viam-works.ru).
    22. Horev A.I. Fundamental'nye i prikladnye raboty po konstrukcionnym titanovym splavam i perspektivnye napravlenija ih razvitija [Fundamental and applied research in structural titanium alloys and perspective directions of development] //Trudy VIAM. 2013. №2. St. 04 (viam-works.ru).
    23. Sidorov V.V., Rigin V.E., Zajcev D.V., Gorjunov A.V. Formirovanie nanostrukturiro-vannogo sostojanija v litejnom zharoprochnom splave pri mikrolegirovanii ego lantanom [Formation of nanostructured state in casting superalloy with microalloying its lanthanum] //Trudy VIAM. 2013. №1. St. 01 (viam-works.ru).
    24. Horev A.I., Nochovnaja N.A., Jakovlev A.L. Mikrolegirovanie redkozemel'nymi metallami titanovyh splavov [Microalloying with rare earth metals titanium alloys] //Aviacionnye materialy i tehnologii. 2012. №S. S. 206–212.

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DOI: 10.18577/2071-9140-2014-0-4-31-36

UDC: 669.018.44:669.017.165

Pages:: 31-36

A.B. Echin1, Yu.A. Bondarenko1

[1] Federal state unitary enterprise «All-Russian Scientific-Research Institute of Aviation Materials» of National Research Center «Kurchatov Institute»

New industrial high-gradient UVNS-6 unit for manufacture of GTE blades and other parts from casting heat-resistant and intermetallic alloys with single-crystal structure

A description of high-gradient directional solidification method for casting of gas turbine engines parts is represented. Dependences of segregation coefficient for some nickel rhenium-containing alloys on directional solidification conditions are given. Advantages and technical characteristics of a new industrial high-gradient UVNS-6 unit were considered. Curves of temperature distribution along the furnace heat assembly height were plotted. For evaluation of quality of the manufactured alloy structure a microstructural analysis of specimens, produced using this unit was fulfilled with a measurement of interdendritic distance. To assess the quality of the received the structure of the alloy held samples in this installation, measuring interdendritic distance. Conclusions were made about a high quality of the manufactured castings.

Keywords: temperature gradient, directional solidification, interdendritic distance, microstructure, single crystal

Reference List

    1. Litye lopatki gazoturbinnyh dvigatelej: splavy, tehnologii, pokrytija [Alloy blades of gas turbine engines, alloys, technology, coating] /Pod obshh. red. E.N. Kablova. 2-e izd. M.: Nauka. 2006. 632 s.
    2. Bondarenko Ju.A. Perspektivy tehnologii napravlennoj kristallizacii krupnogabaritnyh rabochih lopatok nazemnyh gazovyh turbin [Prospects for technology oriented crystallization of rotor blades of large terrestrial gas turbine] //Metallovedenie. 1998. №7. S. 21–25.
    3. Bondarenko Ju.A., Kablov E.N., Morozova G.I. Vlijanie vysokogradientnoj napravlennoj kristallizacii na strukturu i fazovyj sostav zharoprochnogo splava tipa Rene N5 [Influence of high-gradient directional solidification on the structure and phase composition of the superalloy Rene N5 type] //MiTOM. 1999. №2. S. 15–18.
    4. Kablov E.N., Svetlov I.L., Petrushin N.V. Nikelevye zharoprochnye splavy dlja lit'ja lopatok s napravlennoj i monokristallicheskoj strukturoj (Chast' II) [Nickel superalloys for casting of blades with directional and single-crystal structure] //Materialovedenie. 1997. №5. S. 14–16.
    5. Pankratov V.A., Kablov E.N. Inkubator dlja turbinnyh lopatok [Incubator for turbine blades] //Nauka i zhizn'. 1991. №8. S. 62–64.
    6. Bondarenko Ju.A., Echin A.B., Surova V.A., Narskij A.R. O napravlennoj kristallizacii zharoprochnyh splavov s ispol'zovaniem ohladitelja [On the directional solidification of superalloys using cooler] //Litejnoe proizvodstvo. 2011. №5. S. 36–39.
    7. Kablov E.N., Gerasimov V.V., Visik E.M., Demonis I.M. Rol' napravlennoj kristallizacii v resursosberegajushhej tehnologii proizvodstva detalej GTD [The role of directional solidification in resource saving technologies of GTE parts] //Trudy VIAM. 2013. №3. St. 01
    (viam-works.ru).
    8. Belikov A.V., Gerasimov V.V., Visik E.M. Tehnologija poluchenija obrazcov dlja attestacii zharoprochnyh splavov, vyplavlennyh s primeneniem othodov litejnogo proizvodstva zavodov otrasli [Technology of obtaining samples for certification superalloys melted using waste foundry industry plants] //Trudy VIAM. 2013. №6. St. 02 (viam-works.ru).
    9. Kablov E.N., Bondarenko Ju.A. Novoe v tehnologii proizvodstva lopatok GTD [New technologies in the production of gas turbine engine blades] //Ajerokosmicheskij kur'er. 1999. №2.
    S. 60–62.
    10. Bondarenko Ju.A., Kablov E.N. Napravlennaja kristallizacija zharoprochnyh splavov s povyshennym temperaturnym gradientom [Directional solidification of superalloys with a high temperature gradient] //MiTOM. 2002. №7. S. 20–23.
    11. Bondarenko Ju.A., Echin A.B., Surova V.A., Narskij A.R. Vlijanie uslovij napravlennoj kristallizacii na strukturu detalej tipa lopatki GTD [Influence of directional solidification conditions on the structure of parts such as blades of GTE] //Litejnoe proizvodstvo. 2012. №7. S. 14–16.
    12. Kablov E.N., Bondarenko Ju.A., Surova V.A. Osobennosti vysokogradientnoj napravlennoj kristallizacii i oborudovanie dlja lit'ja monokristallicheskih obrazcov i turbinnyh lopatok iz zharoprochnyh splavov, soderzhashhih renij [Features high-gradient directional solidification and equipment for casting of single-crystal turbine blades and high-temperature alloys containing rhenium] /V kn.: Litejnye zharoprochnye splavy. Jeffekt S.T. Kishkina: nauch.-tehn. sb. M.: Nauka. 2006. S. 194–205.
    13. Kablov E.N., Bondarenko Ju.A., Kablov D.E. Osobennosti struktury i zharoprochnyh svojstv monokristallov <001> vysokorenievogo nikelevogo zharoprochnogo splava, poluchennogo v uslovijah vysokogradientnoj napravlennoj kristallizacii [Features of the structure and properties of single crystals of high-temperature <001> vysokorenievogo nickel superalloy obtained under high-gradient directional solidification] //Aviacionnye materialy i tehnologii. 2011. №4. S. 25–31.
    14. Kablov E.N., Bondarenko Ju.A., Echin A.B., Surova V.A. Razvitie processa napravlennoj kristallizacii lopatok GTD iz zharoprochnyh splavov s monokristallicheskoj i kompozicionnoj strukturoj [The development process of directional solidification of GTE blades with a single-crystal superalloys and composite structure] //Aviacionnye materialy i tehnologii. 2012. №1. S. 3–8.
    15. Echin A.B., Bondarenko Ju.A. Promyshlennaja vysokogradientnaja ustanovka napravlennoj kristallizacii UVNS-6 [Industrial installation of high-gradient directional solidification UVNS-6] //Metallurgija mashinostroenija. 2013. №3. S. 32–34.
    16. Bazyleva O.A., Bondarenko Ju.A., Timofeeva O.B., Chabina E.B. Intermetallidnye kompozicii na osnove Ni3Al, legirovannye reniem [Intermetallic based compositions Ni3Al, alloyed with rhenium] //Metallurgija mashinostroenija. 2011. №4. S. 30–34.
    17. Bazyleva O.A., Bondarenko Ju.A., Kalicev V.A., Arginbaeva Je.G. Vlijanie vysokotemperaturnoj gazostaticheskoj obrabotki na svojstva intermetallidnogo splava VKNA-1V [Effect of high temperature gas-static treatment on the properties of intermetallic alloys VKNA-1B] //Litejnoe proizvodstvo. 2011. №9. S. 5–8.
    18. Bazyleva O.A., Bondarenko Ju.A., Timofeeva O.B., Hvackij K.K. Vlijanie kristallograficheskoj orientacii na strukturu i svojstva splava VKNA-1V [Effect of crystallographic orientation on the structure and properties of the alloy VKNA-1B] //Metallurgija mashinostroenija. 2012. №4. S. 8–12.
    19. Bondarenko Ju.A., Bazyleva O.A., Echin A.B. i dr. Vysokogradientnaja napravlennaja kristallizacija detalej iz splava VKNA-1V [High-gradient directional solidification of the alloy components VKNA-1B] //Litejnoe proizvodstvo. 2012. №6. S. 12–16.
    20. Kablov E.N., Bondarenko Ju.A., Echin A.B. i dr. Razvitie processa napravlennoj kristallizacii lopatok GTD iz zharoprochnyh i intermetallidnyh splavov s monokristallicheskoj strukturoj [The development process of directional solidification of high-temperature gas turbine engine blades and intermetallic alloys with a single-crystal structure] //Vestnik MGTU im. N.Je. Baumana. Ser. Mashinostroenie. 2011. №SP2. S. 20–25.
    21. Kablov E.N. Strategicheskie napravlenija razvitija materialov i tehnologij ih pererabotki na period do 2030 goda [Strategic directions of development of materials and technologies of their processing for the period up to 2030] //Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
    22. Kablov E.N., Petrushin N.V., Svetlov I.L., Demonis I.M. Nikelevye litejnye zharoprochnye splavy novogo pokolenija [Nickel superalloys foundries new generation] //Aviacionnye materialy i tehnologii. 2012. №S. S. 36–52.
    23. Bazyleva O.A., Arginbaeva Je.G., Turenko E.Ju. Zharoprochnye litejnye intermetallidnye splavy [Heat-resistant casting intermetallic alloys] //Aviacionnye materialy i tehnologii. 2012. №S. S. 57–60.

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6.

DOI: 10.18577/2071-9140-2014-0-4-37-42

UDC: 621.793

Pages:: 37-42

V.A. Ilyin1, A.V. Panarin1

[1] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru

Aluminum coatings and methods of their manufacture

Different methods of aluminum coating manufacture are presented. Basic features of each of them are described. Some properties of the obtained aluminum coatings, but also variants of their application in industry are considered.

Keywords: aluminum coating, metallization, aluminizing

Reference List

    1. Kablov E.N. Strategicheskie napravlenija razvitija materialov i tehnologij ih pererabotki na period do 2030 goda [Strategic directions of development of materials and technologies to process them for the period up to 2030] //Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
    2. Bahvalov G.T. Zashhita metallov ot korrozii [Protection of metals from corrosion]. M.: Metallurgija. 1964. 290 s.
    3. Koshelev V.N., Gubenkova O.A. Issledovanie zashhitnoj sposobnosti piroliticheskih aljuminievyh pokrytij na stali 30HGSA [The protective ability of pyrolytic aluminum coatings on steel 30KhGSA] //Aviacionnye materialy i tehnologii. 2009. №1. S. 6–10.
    4. Ulig G.G., Revi R.U. Korrozija i bor'ba s nej. Vvedenie v korrozionnuju nauku i tehniku [Corrosion and the fight against it. Introduction to corrosion science and technology]. L.: Himija. 1989. 456 s.
    5. Kablov E.N. Korrozija ili zhizn' [Corrosion or life] //Nauka i zhizn'. 2012. №11. S. 16–21.
    6. Dric M.E., Rajtbarg L.H. Aljuminievye splavy: svojstva, obrabotka, primenenie [Aluminum Alloys: Properties, processing, application]. M.: Metallurgija. 1979. 678 s.
    7. Peresypkin V.I. Prochnost' korpusa morskih sudov i zashhita ot korrozii [Strength of ship hulls and corrosion protection]: Sb. nauch. tr. M.: Transport. 1990. 121 s.
    8. Kudinov V.V., Ivanov V.M. Nanesenie plazmoj tugoplavkih pokrytij [Application of plasma refractory coatings]. M.: Mashinostroenie. 1981. 192 s.
    9. Kablov E.N., Mubojadzhjan S.A. Zharostojkie i teplozashhitnye pokrytija dlja lopatok turbiny vysokogo davlenija perspektivnyh GTD [Heat-resistant and heat-resistant coatings for high-pressure turbine blades looking GTE] //Aviacionnye materialy i tehnologii. 2012. №S. S. 60–71.
    10. Anipchenko L.A., Kostyshev V.A. Teplozashhitnye pokrytija dlja povyshenija nadezhnosti raboty dizel'nyh dvigatelej [Thermal barrier coating for improving the reliability of the diesel engines] /V sb. dokl. Mezhdunarodnoj nauchn.-tehn. konf. «Problemy i perspektivy razvitija dvigatelestroenija». V 2 ch. Samara: SGAU. 2009. Ch. 1. S. 97–98.
    11. Mubojadzhjan S.A., Galojan A.G. Kompleksnye termodiffuzionnye zharostojkie po-krytija dlja bezuglerodistyh zharoprochnyh splavov na nikelevoj osnove [Integrated heat-resistant coatings for thermal diffusion of carbon-free heat-resistant nickel-based alloys] //Aviacionnye materialy i tehnologii. 2012. №3. S. 25–30.
    12. Sinjavskij V.S., Semenov A.M. Optimizacija himicheskogo sostava materiala plaki-rovki listov iz splava 1420 s cel'ju zashhity ot korrozionnyh porazhenij [Optimization of the chemical composition of the material cladding sheets of alloy 1420 to protect it from corrosion damages] //Tehnologija legkih splavov. 2008. №2. S. 115–119.
    13. Razuvaev G.A., Gribov B.G. i dr. Metalloorganicheskie soedinenija v jelektronike [Organometallic compound electronics]. M.: Nauka. 1972. 479 c.
    14. Razuvaev G.A. Primenenie metalloorganicheskih soedinenij dlja poluchenija neorganicheskih pokrytij i materialov [The use of organometallic compounds for the preparation of inorganic materials and coatings]. M.: Nauka. 1986. 256 s.
    15. Zemskov G.V., Artjushhenko N.I. Osazhdenie aljuminija iz gazovoj fazy [Deposition aluminum gas phase] //Zashhita metallov. 1970. №4. C. 473–474.
    16. Koshelev V.N. Osobennosti tehnologii nanesenija piroliticheskih aljuminievyh pokrytij [Technology features pyrolytic deposition of aluminum coatings] //Aviacionnye materialy i tehnologii. 2009. №2. S. 10–14.
    17. Plihunov V.V., Petrov L.M. i dr. Oborudovanie, tehnologii i metody kontrolja dlja osushhestvlenija kompleksnogo podhoda k formirovaniju mnogofunkcional'nyh pokrytij i modificirovannyh sloev metodom vakuumnoj ionno-plazmennoj obrabotki [Equipment, technology and methods of control for an integrated approach to the formation of multifunctional coatings and modified layers by vacuum ion-plasma treatment] /V sb. dokl. VIII nauch. konf. po gidroaviacii «Gidroaviasalon–2010». M.: CAGI. 2010. S. 188–193.
    18. Shluger M.A. Gal'vanicheskie pokrytija v mashinostroenii. Spravochnik [Electroplating in engineering]. M.: Mashinostroenie. 1985. 248 s.
    19. Simanavichjus L.Je., Karnavichus A.P. Jelektroosazhdenie aljuminija iz o-, m-, p-ksilol'nyh rastvorov AlBr3 i nekotorye svojstva pokrytij [The electrodeposition of aluminum from o-, m-, p-xylene solution AlBr3 and some properties of coatings] //Trudy AN LitSSR. Ser. B. 1971. T. 1(64). S. 83–93.
    20. Ersatz für Cadmiumueberzuge in der Luftfahrt //Galvanotechnik. 1991. 82. №5. P. 1559.
    21. Shavkunov S.P., Chernyshev V.E. Issledovanie jelektrohimicheskih prevrashhenij v ortoksilol'nom jelektrolite aljuminirovanija i vlijanie sledov vody na jeti processy [Investigation of electrochemical reactions in o-xylene electrolyte aluminizing and influence of traces of water on these processes] //Vestnik Permskogo universiteta. Ser. «Himija». 2011. №3. S. 39–46.
    22. Fischer I. Fortschritte bei der Verfahrenstechnik der galvanischen Aluminierung //Galvanotechnik. 1997. 88. №6. P. 1852.
    23. Mubojadzhjan S.A., Aleksandrov D.A. i dr. Zashhitnye i uprochnjajushhie ionno-plazmennye pokrytija dlja lopatok i drugih otvetstvennyh detalej kompressora GTD [Protecting and strengthening the ion-plasma coatings for blades and other critical parts of the compressor turbine engine] //Aviacionnye materialy i tehnologii. 2012. №S. S. 71–81.
    24. Mubojadzhjan S.A., Budinovskij S.A. i dr. Poluchenie keramicheskih teplozashhitnyh pokrytij dlja rabochih lopatok turbin aviacionnyh GTD magnetronnym metodom [Preparation of ceramic thermal barrier coatings for turbine blades of aircraft GTE magnetron sputtering] //Aviacionnye materialy i tehnologii. 2012. №4. S. 3–8.
    25. Bogdanovich V.I., Dokukina I.A. i dr. Teplozashhitnye plazmennye pokrytija detalej dvigatelej [Thermic plasma coating of engine parts] /V sb. dokl. Mezhdunarodnoj nauch.-tehn. konf. «Problemy i perspektivy razvitija dvigatelestroenija». V 2 ch. Samara: SGAU. 2009. Ch. 1. S. 49–50.
    26. Plihunov V.V., Petrov L.M. i dr. Kombinirovannaja vakuumnaja ionno-plazmennaja obrabotka poverhnosti konstrukcionnyh metallicheskih materialov [Combined vacuum ion-plasma surface treatment of metallic structural materials] /V sb. dokl. VIII nauch. konf. po gidroaviacii «Gidroaviasalon–2010». M.: CAGI. 2010. S. 194–198.
    27. Migranov M.Sh., Shuster L.Sh. Primenenie instrumental'nyh nanokristallicheskih pokrytij dlja intensifikacii metalloobrabotki detalej GTD [Application tool nanocrystalline coatings for GTE parts intensification metalworking] /V sb. dokl. Mezhdunarodnoj nauch.-tehn. konf. «Problemy i perspektivy razvitija dvigatelestroenija». V 2 ch. Samara: SGAU. 2009. Ch. 2. S. 122–123.
    28. Belous V.Ja., Varlamova V.E. i dr. Ionno-plazmennye pokrytija dlja zashhity ot korrozii kompressornyh lopatok i drugih detalej GTD, jekspluatirujushhihsja vo vseklimaticheskih uslovijah [Ion-plasma coatings for corrosion protection of compressor blades and other parts of GTE, operated in all climate conditions] //Korrozija: materialy, zashhita. 2012. №1. S. 20–24.
    29. Zamaletdinov I.I., Smetkin A.A. i dr. Vlijanie sostojanija poverhnosti stali 20H3MVF-Sh na korrozionnye svojstva nanopokrytija TiAlN, nanesennogo metodom magnetronnogo raspylenija [Influence of surface condition became 20H3MVF-W on the corrosion properties of nano-coating TiAlN, deposited by magnetron sputtering] //Korrozija: materialy, zashhita. 2013. №3. S. 34–41.
    30. Krasnojarskij V.V., Mazin V.A. i dr. Poristost' i zashhitnoe dejstvie aljuminievyh gal'vanicheskih pokrytij [Porosity and the protective effect of aluminum plating] //Zashhita metallov. 1992. T. 28. №1. S. 125–128.

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7.

DOI: 10.18577/2071-9140-2014-0-4-43-47

UDC:

Pages:: 43-47

A.A. Platonov1

[1] Federal state unitary enterprise «All-Russian Scientific-Research Institute of Aviation Materials» of National Research Center «Kurchatov Institute»

Polymer composite materials on a base of stitched preforms with high impact resistance

The article provides a review of one of varieties of 3-dimensional reinforcement of PCM - stitching of preforms, providing strengthening of traditional laminated composite, thereby improving its resistance to delamination. The influence of stitching density and thickness of stitching thread on an impact resistance and compression strength after impact are considered.

Keywords: сomposite materials, 3-dimensional reinforcement, stitched preforms, RFI, compression after impact

Reference List

    1. Kablov E.N. Strategicheskie napravlenija razvitija materialov i tehnologij ih pererabotki na period do 2030 goda [Strategic directions of development of materials and technologies of their processing for the period up to 2030] //Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
    2. Kablov E.N. Himija v aviacionnom materialovedenii [Chemistry in aviation materials] //Rossijskij himicheskij zhurnal. 2010. T. LIV. № 1. S. 3–4.
    3. Platonov A.A., Kogan D.I., Dushin M.I. Izgotovlenie trehmernoarmirovannyh PKM metodom propitki plenochnym svjazujushhim [Making trehmernoarmirovannyh RMB by impregnation film bonding] //Plasticheskie massy. 2013. №12. S. 56–61.
    4. Tan K.T., Watanabe N., Iwahori Y. X-ray radiography and micro computed tomography examination of damage characteristics in stitched composites subjected to impact loading //Composites. B. 2011. V. 42. P. 874–84.
    5. Tan K.T., Watanabe N., Iwahori Y. Experimental investigation of bridging law for single stitch fibre using interlaminar tension test //Composite Structures. 2010. V. 92. P. 1399–1409.
    6. Mouritz A.P., Cox B.N. A mechanistic interpretation of the comparative in-plain mechanical properties of 3D woven, stitched and pinned composites //Composites. A. 2010. V. 41. P. 709–728.
    7. Mouritz A.P., Cox B.N. A mechanistic approach to the properties of stitched laminates //Composites. A. 2000. V. 31. P. 1–27.
    8. Scarponi C., Perillo A.M., Cutillo L., Foglio C. Advanced TTT composite materials for aeronautical purposes: compression after impact (CAI) behavior //Composites. B. 2007. V. 38. P. 258–264.
    9. Zhelezina G.F. Osobennosti razrushenija organoplastikov pri udarnyh vozdejstvijah [Features destroying organic plastics under Impact] //Aviacionnye materialy i tehnologii. 2012. №S.
    S. 272–277.
    10. Zhao N., Hartmut R., Herzberga C. et al. Stitched glass/PP composite. Part I: Tensile and impact properties //Composites. A. 2012. V. 40. P. 635–643.
    11. Erasov V.S., Krylov V.D., Panin S.V., Goncharov A.A. Ispytanija polimernogo kompozicionnogo materiala na udar padajushhim gruzom [Test polymeric composite material falling weight impact] //Aviacionnye materialy i tehnologii. 2013. №3. S. 60–64.
    12. Hrul'kov A.V., Dushin M.I., Popov Ju.O., Kogan D.I. Issledovanie i razrabotka avtoklavnyh i bezavtoklavnyh tehnologij formovanija PKM [Research and development of autoclave and non-autoclave molding technology PKM] //Aviacionnye materialy i tehnologii. 2012. №S. S. 292–301.
    13. Zhou G. Effect of impact damage on residual compressive strength of glassfibre reinforced polyester (GFRP) laminates //Composite Structures. 1996. V. 35. P. 171–181.
    14. Byun J.H., Song S.W., Lee C.H. et al. Impact properties of laminated composites with stitching fibers //Composite Structures. 2006. V. 76. P. 21–27.
    15. Beier U., Fischer F., Sandler J.K.W. et al. Mechanical performance of carbon fibre-reinforced composites based on stitched preforms //Composites. A. 2007. V. 38. P. 1655–1663.
    16. Caneva C., Olivieri S., Santulli C., Bonifazi G. Impact damage evaluation on advanced stitched composites by means of acoustic emission and image analysis //Composite Structures. 1993.
    V. 25. P. 121–128.
    17. Chursova L.V., Dushin M.I., Kogan D.I. i dr. Plenochnye svjazujushhie dlja RFI-tehnologii [Film binders for RFI-technology] //Rossijskij himicheskij zhurnal. 2010. №1. S. 63–66.
    18. Dushin M.I., Muhametov R.R., Platonov A.A., Merkulova Ju.I. Issledovanie fil'tracionnyh harakteristik armirujushhih napolnitelej i svjazujushhih pri razrabotke tehnologii bezavtoklavnogo formovanija polimernyh kompozicionnyh materialov [Investigation of filtration characteristics of reinforcing fillers and binders in the development of technology bezavtoklavnogo forming polymer composites] //Aviacionnye materialy i tehnologii. 2013. №2. S. 22–25.
    19. Muhametov R.R., Ahmadieva K.R., Kim M.A., Babin A.N. Rasplavnye svjazujushhie dlja perspektivnyh metodov izgotovlenija PKM novogo pokolenija [Melt binders for advanced methods of manufacturing a new generation of PCM] //Aviacionnye materialy i tehnologii. 2012. №S.
    S. 260–265.
    20. Babin A.N. Svjazujushhie dlja polimernyh kompozicionnyh materialov novogo pokolenija [Binders for polymer composite materials of new generation] //Trudy VIAM. 2013. №4
    (viam-works.ru).
    21. Jepoksidnaja kompozicija [Epoxy compositions]: pat. 2447104 Ros. Federacija; opubl. 05.10.2010.
    22. Jepoksidnoe svjazujushhee, prepreg na ego osnove i izdelie, vypolnennoe iz nego [Epoxy binder prepreg on its base, and article made from it]: pat. 2424259 Ros. Federacija; opubl. 22.10.2009.
    23. ASTM D 7136/D 7136M. Standard Test Method for Measuring the Damage Resistance of a Fi-ber-Reinforced Polymer Matrix Composite to a Drop-Weight Impact Event. ASTM International. 2007.
    24. ASTM D 7137/D 7137M. Standard Test Method for Compressive Residual Strength Properties of Damaged Polymer Matrix Composite Plates. ASTM International. 2007.

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DOI: &nbsp;10.18577/2071-9140-2014-0-4-48-52

UDC: 678.8

Pages:: 48-52

A.V. Borshchev1, Y.A. Gusev1

[1] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru

Development and implementation of PCM in automotive industry. Varieties of HP-RTM processes

To reduce a fuel consumption of cars, automakers have to decrease a mass of body parts. Polymeric composite materials (PCM) can serve as an alternative to metals, they have better corrosion and fatigue properties, a ratio of mass to strength and good shock resistance. However, to use PCM high potential entirely in automotive industry, it is necessary to implement high-production and low-cost technologies. All world auto giants for a long time have already been looking for ways to start a production of body parts from composite materials. For example, BMW has already begun a commercialization of i8 and i3, they are completely carbon fiber models.This article examines an impact of forming processes for production of car parts, on impact strength, that characterizes an absorption of energy in collision.

Keywords: composite materials, resin transfer molding, HP-IRTM, HP-CRTM processes, automotive industry

Reference List

    1. Kablov E.N. Strategicheskie napravlenija razvitija materialov i tehnologij ih pererabotki na period do 2030 goda [Strategic directions of development of materials and technologies of their processing for the period up to 2030] //Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
    2. Goncharenko A. Karbonovoe budushhee [Carboxylic future] //Kompozitnyj mir. 2013. №5. S. 50–51.
    3. Gunjaev G.M., Kablov E.N., Aleksashin V.M. Modificirovanie konstrukcionnyh ugleplastikov uglerodnymi nanochasticami [Modification of structural CFRP carbon nanoparticles] //Rossijskij himicheskij zhurnal. 2010. T. LIV. №1. S. 5–11.
    4. Christian F. Lightweight automotive design with HP-RTM //Reinforced Plastics. 2011. P. 29–31.
    5. Chensong Dong. A modified rule of mixture for the vacuum-assisted resin transfer moulding process simulation //Composites Science and Technology. 2008. V. 68. №9. P. 2125–2133.
    6. Simacek P., Suresh G., Stanley A. Modeling Flow in Compression Resin Transfer Molding for Manufacturing of Complex Lightweight High-Performance Automotive Parts //Journal of Composite Materials. 2008. №42. P. 2523–2545.
    7. Dushin M.I., Hrul'kov A.V., Muhametov R.R., Chursova L.V. Osobennosti izgotovlenija izdelij iz PKM metodom propitki pod davleniem [Features of the manufacture of the PCM by pressure impregnation] //Aviacionnye materialy i tehnologii. 2012. №1. C. 18–26.
    8. Neljub V.A., Grashhenkov D.V., Kogan D.I., Sokolov I.A. Primenenie prjamyh metodov formovanija pri proizvodstve krupnogabaritnyh detalej iz stekloplastikov [The use of direct methods of molding in the manufacture of large parts of the GRP] //Himicheskaja tehnologija. 2012.
    T. 13. №12. S. 17–23.
    9. Hrul'kov A.V., Dushin M.I., Popov Ju.O., Kogan D.I. Issledovanija i razrabotka avto-klavnyh i bezavtoklavnyh tehnologij formovanija PKM [Research and development of autoclave and non-autoclave molding technology PCM] //Aviacionnye materialy i tehnologii. 2012. №S. S. 292–301.
    10. Dushin M.I., Muhametov R.R., Platonov A.A., Merkulova Ju.I. Issledovanie fil'tracionnyh harakteristik armirujushhih napolnitelej i svjazujushhih pri razrabotke tehnologii bezavtoklavnogo formovanija polimernyh kompozicionnyh materialov [Investigation of filtration characteristics of reinforcing fillers and binders in the development of technology bezavtoklavnogo forming polymer composites] //Aviacionnye materialy i tehnologii. 2013. №2. S. 22–25.
    11. Mouton S., Teissandier D., Sebastian P., Nadeau J.P. Manufacturing requirements in design: the rtm process in aeronautics //Composites. Part A: Applied Science and Manufacturing. 2010. V. 41. №1. P. 125–130.
    12. Borshhev A.V., Gusev Ju.A. Osobennosti formovanija kompozicionnyh izdelij s primeneniem vysokogo davlenija v RTM-tehnologii dlja proizvodstva avtomobil'nyh detalej [Features molded composite products using high-pressure RTM-technology for the production of automotive parts] //Kompozitnyj mir. 2013. №5. S. 40–44.
    13. Muhametov R.R., Ahmadieva K.R., Chursova L.V., Kogan D.I. Novye polimernye svjazujushhie dlja perspektivnyh metodov izgotovlenija konstrukcionnyh voloknistyh PKM [New polymeric binders for advanced manufacturing methods of structural fibrous PCM] //Aviacionnye materialy i tehnologii. 2011. №2. S. 38–42.
    14. Muhametov R.R., Merkulova Ju.I., Chursova L.V. Termoreaktivnye polimernye svjazujushhie s prognoziruemym urovnem reologicheskih i deformativnyh svojstv [Thermoset polymer due to the projected level of rheological and deformation properties] //Klei. Germetiki. Tehnologii. 2012. №5. S. 19–24.
    15. Muhametov R.R., Ahmadieva K.R., Kim M.A., Babin A.N. Rasplavnye svjazujushhie dlja perspektivnyh metodov izgotovlenija PMK novogo pokolenija [Melt binders for advanced methods of manufacturing a new generation of PCM] //Aviacionnye materialy i tehnologii. 2012. №S. S. 260–265.
    16. GOST 4647–80 Izmenenie №2. Plastmassy. Metod opredelenija udarnoj vjazkosti po Sharpi [Changing №2. Plastic. Method of determining the Charpy impact strength].
    17. Erasov V.S., Grinevich A.V., Senik V.Ja. et al. Raschetnye znachenija harakteristik prochnosti aviacionnyh materialov [Calculated values of the strength characteristics of aircraft materials] //Aviacionnye materialy i tehnologii. 2012. №2. S. 14–16.
    18. Deleglise M. Modeling of high speed RTM injection with highly reactive resin with on-line mixing //Applied Science and Manufacturing. 2011. V. 42 (10). P. 1390–1397.
    19. Graf M., Fries E., Renkl J. et al. High-Pressure Resin Transfer Molding – Process Advancements /In: 10-th SPE ACCE. 2010. P. 15–16.
    20. Babin A.N. Svjazujushhie dlja polimernyh kompozicionnyh materialov novogo pokolenija [Binders for polymer composite materials of new generation] //Trudy VIAM. 2013. №4 (viam-works.ru).
    21. Jepoksidnaja kompozicija [Epoxy compositions]: pat. 2447104 Ros. Federacija; opubl. 05.10.2010.
    22. Jepoksidnoe svjazujushhee, prepreg na ego osnove i izdelie, vypolnennoe iz nego [Epoxy binder prepreg on its base, and article made from it]: pat. 2424259 Ros. Federacija; opubl. 22.10.2009.

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DOI: 10.18577/2071-9140-2014-0-4-53-57

UDC: 678.8

Pages:: 53-57

R.R. Mukhametov1, E.V. Dolgova2, Yu.I. Merkulova2, M.I. Dushin2

[1] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru
[2] Federal state unitary enterprise «All-Russian Scientific-Research Institute of Aviation Materials» of National Research Center «Kurchatov Institute»

Development of heat-resistant bismaleimide binder for composites of aeronautical applications

One of the most promising ways to create heat-resistant bismaleimide binder was presented. A possibility to increase a fracture toughness of poly-bismaleimide using compositions of elastomers was shown. The process of structurization of binder, its thermal and heat resistance was studied. The principal possibility of creating plastics based on bismaleimide binder with operational temperature up to 250°C was demonstrated.

Keywords: thermoset polymers, bismaleimides, polymeric binders, fracture toughness, composite material, thermal analysis

Reference List

    1. Kablov E.N. Strategicheskie napravlenija razvitija materialov i tehnologij ih pererabotki na period do 2030 goda [Strategic directions of development of materials and technologies of their processing for the period up to 2030] //Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
    2. Kablov E.N., Kondrashov S.V., Jurkov G.Ju. Perspektivy ispol'zovanija uglerodsoderzhashhih nanochastic v svjazujushhih dlja polimernyh kompozicionnyh materialov [Prospects for the use of carbonaceous nanoparticles in relation to polymer composites] //Rossijskie nanotehnologii. 2013. T. 8. №3–4. S. 24–42.
    3. Kablov E.N., Kondrashov S.V., Yurkov G.Y. Prospects of using carbonaceous nanoparticles in binders for polymer composites //Nanotechnologies in Russia. 2012. V. 8. №3–4. P. 163–185.
    4. Muhametov R.R., Ahmadieva K.R., Chursova L.V., Kogan D.I. Novye polimernye svjazujushhie dlja perspektivnyh metodov izgotovlenija konstrukcionnyh voloknistyh PKM [New polymeric binders for advanced manufacturing methods of structural fibrous PCM] //Aviacionnye materialy i tehnologii. 2011. №2. S. 38–42.
    5. Muhametov R.R., Ahmadieva K.R., Kim M.A., Babin A.N. Rasplavnye svjazujushhie dlja perspektivnyh metodov izgotovlenija PKM novogo pokolenija [Melt binders for advanced methods of manufacturing a new generation of PCM] //Aviacionnye materialy i tehnologii. 2012. №S. S. 260–265.
    6. Dushin M.I., Muhametov R.R., Platonov A.A., Merkulova Ju.I. Issledovanie fil'tracionnyh harakteristik armirujushhih napolnitelej i svjazujushhih pri razrabotke tehnologii bezavtoklavnogo formovanija polimernyh kompozicionnyh materialov [Investigation of filtration characteristics of reinforcing fillers and binders in the development of technology bezavtoklavnogo forming polymer composites] //Aviacionnye materialy i tehnologii. 2013. №2. S. 22–25.
    7. Zheleznjak V.G., Muhametov R.R., Chursova L.V. Issledovanie vozmozhnosti sozdanija termoreaktivnogo svjazujushhego na rabochuju temperaturu do 400°C [Investigation of the possibility of creating a thermosetting binder for working temperatures up to 400°C] //Aviacionnye materialy i tehnologii. 2013. №S2. S. 58–61.
    8. Muhametov R.R., Merkulova Ju.I., Chursova L.V. Termoreaktivnye polimernye svjazujushhie s prognoziruemym urovnem reologicheskih i deformativnyh svojstv [Thermoset polymer due to the projected level of rheological and deformation properties] //Klei. Germetiki. Tehnologii. 2012. №5. S. 19–21.
    9. Prohorova E.V., Muhametov R.R. Modifikacija triazinovyh kompozicij [Modification triazine compositions] //Trudy VIAM. 2013. №9. St. 06 (viam-works.ru).
    10. Bejder Je.Ja., Petrova G.N., Izotova T.F., Gureeva E.V. Kompozicionnye termoplastichnye materialy i penopoliimidy [Composite thermoplastic materials and penopoliimidy] //Trudy VIAM, 2013. №11. St. 01 (viam-works.ru).
    11. Xiong X.H., Chen P., Zhang J.X. et al. Cure kinetics and thermal properties of novel bismaleimides containing phthalide cardo structure //Thermochim. Acta. 2011. V. 514. P. 44–50.
    12. Xiong X.H., Chen P., Yu Q. Synthesis and properties of chain-extended bismaleimide resins containing phthalide cardo structure //Polym. Int. 2010. V. 59. P. 1665–1672.
    13. Wu Q.A., Bao J.W., Zhang C. et al. The effect of thermal stability of carbon nanotubes on the flame retardancy of epoxy and bismaleimide/carbon fiber/buckypaper composites //J. Therm. Anal Calorim. 2011. V. 103. P. 237–242.
    14. Gunjaev G.M., Kablov E.N., Aleksashin V.M. Modificirovanie konstrukcionnyh ugleplastikov uglerodnymi nanochasticami [Modification of structural CFRP carbon nanoparticles] //Rossijskij himicheskij zhurnal. 2010. T. LIV. №1. S. 5–11.

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DOI: 10.18577/2071-9140-2014-0-4-58-64

UDC: 678.8:614.814.41

Pages:: 58-64

G.N. Petrova1, E.Ya. Beyder2

[1] Federal state unitary enterprise «All-Russian Scientific-Research Institute of Aviation Materials» of National Research Center «Kurchatov Institute»
[2] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru

Increasing of fire resistance of polybutylene terephthalate (review)

The ways of increasing of fire resistance of polybutyleneterephthalate (PBT) owing to introducing flame retardants into its composition during extrusion are shown. An influence of the way of introducing and composition of flame retardants on strength, deformation and fireproof (combustibility) properties of PBT was considered.

Keywords: polyethers, polybutyleneterephthalate, composite material, flame retardant, fire safety, extrusion

Reference List

    1. Kablov E.N. Strategicheskie napravlenija razvitija materialov i tehnologij ih pererabotki na period do 2030 goda [Strategic directions of development of materials and technologies to process them for the period up to 2030] //Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
    2. Kablov E.N. Himija v aviacionnom materialovedenii [Chemistry aviation materials] //Rossijskij himicheskij zhurnal. 2010. T. LIV. №1. S. 3–4.
    3. Kravchenko T.P., Ermakov S.N., Kerber M.L., Kostjagina V.A. Nauchno-tehnicheskie problemy poluchenija kompozicionnyh materialov na osnove konstrukcionnyh termoplastov [Scientific and technical problems of producing composite materials on the basis of engineering thermoplastics] //Plasticheskie massy. 2010. №10. S. 32–34.
    4. Kryzhanovskij V.K., Burlov V.V., Panimatchenko A.D., Kryzhanovskaja Ju.V. Tehnicheskie svojstva polimernyh materialov [Technical properties of polymeric materials]. SPb.: Professija. 2005. S. 8–16, 44, 45, 69–174.
    5. Sazonov V.V., Gazaev M.M., Mikitaev A.K.Perspektivy primenenija cik-licheskih polibutilentereftalatov [Prospects of application of cyclic polybutylene-terephthalates] /V sb. materialov VI Mezhdunarodnoj nauch.-praktich. konf. «Novye polimernye kompozicionnye materialy». Nal'chik: KBGU. 2010. S. 378–382.
    6. Trostjanskaja E.B., Stepanova M.I., Rassohin G.I. Teplostojkie linejnye polimery [Heat resistant linear polymers]. Rostov-na-Donu: RGASHM. 2002. S. 3–22.
    7. Brandshtetter F. Tendencii i perspektivy razvitija polimernyh materialov [Trends and prospects of polymeric materials] //Polimernye materialy: izdelija, oborudovanie, tehnologii. 2005. №5. S. 2–4.
    8. Kjasova Je.H., Kulova D.H., Molokanov G.O. i dr. Polimer-polimernye smesi na osnove polibutilentereftalata [Polymer-polymer mixtures based on PBT] /V sb. materialov VI Mezhdunarodnoj nauch.-praktich. konf. «Novye polimernye kompozicionnye materialy». Nal'chik: KBGU. 2010. S. 233–235.
    9. Takjeo Jasuda. Ryusan to kogyo //Sulphur. Acid and Ind. 2012. V. 65. №1. Р. 11–14.
    10. Bernhardt Je. Pererabotka termoplastichnyh materialov [Processing of thermoplastic material]: Per. s angl. M.: Himija. 1965. S. 169–581.
    11. Vlasov S.V., Kandyrin L.B., Kuleznev V.N., Markov A.V., Simonov-Emel'janov I.D., Surikov P.V., Ushakova O.B. Osnovy tehnologii pererabotki plastmass [Basics of plastics processing technology]. M.: Himija. 2004. S. 13–41, 334, 438–441, 567.
    12. Shvarc O., Jebeling F.V., Furt B. Pererabotka plastmass [Plastics recycling]: Per. s nem. SPb.: Professija. 2005. S. 31–237.
    13. Markov A.V., Vlasov S.V. Principy vybora polimernyh materialov dlja izgotovlenija izdelij [Principles for selection of polymer materials for the manufacture] //IB Polimernye materialy. 2004. №7 (562). S. 26–28.
    14. Sudarushkin Ju.K., Gudimov M.M., Romanov D.S., Sokolov M.Ju. Prime-nenie lit'evyh polikarbonatov v aviapriborostroenii [Application molded polycarbonate in Aircraft Engineering] //Aviacionnaja promyshlennost. 2003. №2. S. 48–52.
    15. Petrova G.N, Abakumova N.M., Rumjanceva T.V.i dr. Lit'evye termopla-sty s ponizhennoj gorjuchest'ju [Molding thermoplastics with low flammability] /V sb. Aviacionnye materialy i tehnologii. Vyp. Termoplastichnye materialy. M.: VIAM. 2004. S. 21–23.
    16. Mihajlin Ju.A. Termoustojchivye polimery i polimernye materialy [Heat resistant polymers and polymeric materials]. SPb.: Professija. 2006. S. 29–30.
    17. Gal'brajh L.S., Pravednikova O.B., Dutikova O.S. i dr. Snizhenie pozha-roopasnosti polijefirnyh materialov s ispol'zovaniem nanokomponentov ognezamedlitel'noj sistemy [Reduced flammability polyester materials with fire retardant system nanocomponents] //MGTU im. A.N. Kosygina. 2010. Pril. K 90-letiju MGTU im. A.N. Kosygina. S. 51–55.
    18. Petrova G.N., Rumjanceva T.V. i dr. Termojelastoplasty – novyj klass po-limernyh materialov [Thermoplastic elastomers – a new class of polymeric materials] //Aviacionnye materialy i tehnologii. 2010. №4. S. 20–25.
    19. Grashhenkov D.V., Chursova L.V. Strategija razvitija kompozicionnyh i funkcional'nyh materialov [Development Strategy composite and functional materials] //Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
    20. Petrova G.N., Perfilova D.N. i dr. Pozharobezopasnye lit'evye termoplasty i termojelastoplasty [Fireproof molded thermoplastics and thermoplastic elastomers] //Trudy VIAM. 2013. №11.St. 02 (viam-works.ru).
    21. Petrova G.N., Bejder Je.Ja. Lit'evye termoplastichnye materialy aviakosmicheskogo naznachenija [Molded thermoplastic materials aerospace destination] //Rossijskij himicheskij zhurnal. 2010. T. L1V. №1. S. 41–45.
    22. Petrova G.N., Perfilova D.N. Grjaznov V.I., Bejder Je.Ja. Termoplastichnye jelastomery dlja zameny rezin [Thermoplastic elastomers for replacement rubbers] //Aviacionnye materialy i tehnologii. 2012. №S. S. 302–307.
    23. Petrova G.N., Perfilova D.N., Rumjanceva T.V., Bejder Je.Ja. Samozatuha-jushhie termojelastoplasty [Self-extinguishing thermoplastic] //Plasticheskie massy. 2013. №2. S. 5–7.
    24. Petrova G.N., Bejder Je.Ja. Pozharobezopasnye lit'evye termoplasty dlja aviakosmicheskoj tehniki [Fireproof molded thermoplastics for aerospace engineering] //Vse materialy. Jenciklopedicheskij spravoch-nik. 2008. №8. S. 47–49.
    25. Petrova G.N., Rumjanceva T.V., Bejder Je.Ja. Vlijanie modificirujushhih dobavok na pozharobezopasnye svojstva i tehnologichnost' polikarbonata [Influence of modifying additives on the properties and processability fireproof polycarbonate] //Trudy VIAM. 2013. №6. St. 06 (viam-works.ru).
    26. Halturinskij N.A., Rudakova T.A. Fizicheskie aspekty gorenija polimerov i mehanizm dejstvija ingibitorov [Physical aspects of the combustion of polymers and the mechanism of action of inhibitors] //Himicheskaja fizika. 2008. T. 27. №6. S. 73–84.
    27. Gao Feng, Tong Lifang, Fang Zhengping. Effect of a novel phosphorous – nitrogen containing intumescent flame retardant on the fire retardancy and the thermal behavior of poly (butylenes terephthalate) //Polym. Degrad. and Stab. 2006. 91. №6. S. 1295–1299.
    28. Ognestojkaja polimernaja kompozicija i izdelie, vypolnennoe iz nee [Flame retardant resin composition and a product made from there]: pat. 2254349 Ros. Federacija; opubl. 20.06.2005.
    29. Ognestojkaja termoplastichnaja kompozicija i izdelie, vypolnennoe iz nee [Flame retardant thermoplastic composition and article made from there]: pat. 2283327 Ros. Federacija; opubl. 10.09.2005.
    30. Lomakin S.M., Zaikov G.E., Mikitaev A.K. Zamedliteli gorenija dlja polimerov [Retardants for polymers] //Jenciklopedija inzhenera-himika. 2011. №9. S. 22–27.
    31. Gordienko V.P., Sal'nikov V.G. Vlijanie nekotoryh napolnitelej-antipirenov neorganicheskoj prirody na gorjuchest' termoplastichnyh materialov [Effect of some fillers, flame retardants inorganic nature flammability thermoplastic materials] //Plasticheskie massy. 2011. №9. S. 57–60.
    32. Petrova G.N., Barbot'ko S.L., Bejder Je.Ja. i dr. Pozharobezopasnye lit'evye termoplasty [Fireproof molded thermoplastics] //Plasticheskie massy. 2006. №1. S. 46–48.
    33. Polishhuk E.Ju., Balakin V.M., Rukavishnikov A.V. Fosforsoderzhashhie antipireny na osnove karbamidoaminoal'degidnyh oligomerov [Phosphorus-based flame retardants karbamidoaminoaldegidnyh oligomers] /V sb. dokladov V Mezhdunarodnoj konf. «Kompozit–2010» «Perspektivnye polimernye kompozicionnye materialy. Al'ternativnye tehnologii. Pererabotka. Primenenie. Jekologija». Saratov: SGTU. 2010. S. 115–116.
    34. Halturinskij N.A., Rudakova T.A., Popova T.V. Novye vysokojeffektiv-nye antipireny [New high-retardants] /V sb. dokladov ezhegodnoj nauch. konf. otdela «Gorenija i vzryva». M.: IHF RAN. 2011. №4. S. 184–187.
    35. Panova L.G. Razrabotka nauchnyh osnov ognezashhity polimernyh materialov [Development of scientific bases suppressants polymeric materials] //Vestnik SGTU. 2011. №4. Ch. 3. S. 147–151.
    36. Dong Jinhu. Saliao keji //Plast. Sci. and Technol. 2012. V. 40. P. 100–105.
    37. Troitzsch Jürgen. Flammschutzmittel //Kunststoffe. 2002. V. 92. №9. P. 41–44.
    38. Berlin A. Polimery: ispytanie ognem [Polymers: trial by fire] //Nauka v Rossii. 2006. №2. S. 12–17.
    39. Antonov A.V., Il'inyh M.V. Sovremennye tendencii sozdanija polimer-nyh materialov ponizhennoj gorjuchesti [Modern trends in developing polymer materials reduced flammability] /V sb. tezisov dokl. XXI simpoziuma «Sovremennaja himicheskaja fizika». Tuapse. 2009. S. 28.
    40. Serboroh Joseph. Halogen – and red phosphorous free flame retardants devel-oped //Plast. Addit. and Compound. 2004. V. 6. №4. S. 12–14.
    41. Barbot'ko S.L. Puti obespechenija pozharnoj bezopasnosti aviacionnyh materialov [Ways to ensure fire safety of aircraft materials] //Rossijskij himicheskij zhurnal. 2010. T. LIV. №1. S. 121–126.
    42. Mihajlin Ju.A. Pokazateli ognestojkosti PM i metody ih opredelenija [Flamability PM and methods for their determination] //Polimernye materialy. 2011. №8. S. 32–34.
    43. Bejder Je.Ja., Petrova G.N., Izotova T.F., Barbotko S.L. Stekloplastiki na termoplastichnoj mat-rice [Glass-reinforced on thermoplastic matrix] //Trudy VIAM. 2013. №7. St. 03 (viam-works.ru).
    44. Dong Jinhu. Suliao keji Plast //Sci. and Technol. 2012. V. 40. №5. S. 100–105.

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DOI: &nbsp;10.18577/2071-9140-2014-0-4-65-67

UDC: 678.5

Pages:: 65-67

I.V. Parakhin1, A.S. Tumanov1

[1] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru

Phenolic-rubber foamed plastic of higher plasticity

This work is devoted to a manufacture of phenolic-rubber foamed plastic with higher plasticity. Changing of properties and structure of foamed plastic depending on the chosen plasticizer is studied Thermal resistance and complex of physical-mechanical properties of the manufactured phenolic plastic are investigated.

Keywords: phenolic-rubber foamed plastic, technology, plasticity, plasticizer

Reference List

    1. Popov V.A. Gazonapolnennye plastmassy na osnove fenoloal'degidnyh smol i ih sochetanija s vysokopolimerami [Gas-filled plastic based on phenolic resins and combinations thereof with high polymer] //Plasticheskie massy. 1960. №10. S. 20–25.
    2. Spravochnik po plasticheskim massam [Handbook of plastics]: V 2 t. T.2 /Pod red. V.M. Kataeva, V.A. Popova, B.I. Sazhina. 2-e izd., pererab. M.: Himija. 1975. 568 s.
    3. Berlin A.A., Shutov F.A. Penopolimery na osnove reakcionnosposobnyh oligomerov [Foam-based reactive oligomers]. M.: Himija. 1978. 296 s.
    4. Aleksandrov A.Ja., Borodin M.Ja., Pavlov V.V. Konstrukcii s zapolnitelem iz penoplastov [Constructions with aggregate of foams]. M.: Mashinostroenie. 1972. 396 s.
    5. Dvorko I.M., Shhemeleva L.V. Svojstva i primenenie penoplastov Tilen-A na osnove poroshkovyh novolachnyh fenoloformal'degidnyh kompozicij [Properties and application of foams Thielen-A based on phenol-formaldehyde novolak powder compositions] //Plasticheskie massy. 1999. №4. S. 20–21.
    6. Samatadze A.I., Parahin I.V., Porosova N.F., Tumanov A.S. Poluchenie fenolokauchukovyh penoplastov metodom «bessernoj» vulkanizacii [Getting fenolokauchukovyh foams by "bessernoy" vulcanization] //Aviacionnye materialy i tehnologii. 2013. №3. S. 49–52.
    7. Parahin I.V., Tumanov A.S. Fenol'no-kauchukovyj penoplast marki VRP-4 [Phenolic foam rubber stamps VRP-4] //Aviacionnye materialy i tehnologii. 2014. №1. S. 42–46.
    8. Sagomonova V.A., Sytyj Ju.V. Osnovnye principy sozdanija vibropogloshhajushhih materialov aviacionnogo naznachenija [Basic principles of vibration-absorbing materials aviation applications] //Trudy VIAM. 2013. №11. St. 03 (viam-works.ru).
    9. Kompozicija dlja poluchenija penoplasta [A composition for producing foam]: pat. 2477734 Ros. Federacija; opubl. 20.03.2013.
    10. Gorlov Ju.P., Merkin A.P., Ustenko A.A. Tehnologija teploizoljacionnyh materialov [The technology of thermal insulation materials]: Uchebnik dlja vuzov. M.: Strojizdat. 1980. 399 s.
    11. Kablov E.N. Strategicheskie napravlenija razvitija materialov i tehnologij ih pererabotki na period do 2030 goda [Strategic directions of development of materials and technologies of their processing for the period up to 2030] //Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
    12. Kablov E.N. Himija v aviacionnom materialovedenii [Chemistry in aviation materials] //Rossijskij himicheskij zhurnal. 2010. T. LIV. №1. S. 3–4.
    13. Kablov E.N. Materialy i himicheskie tehnologii dlja aviacionnoj tehniki [Materials and chemical technologies for aircraft equipment] //Vestnik Rossijskoj akademii nauk. 2012. T. 82. №6. S. 520–530.
    14. Zastrogina O.B., Shvec N.I., Postnov V.I., Serkova E.A. Fenolformal'degidnye svjazujushhie dlja novogo pokolenija materialov inter'era [Phenol-formaldehyde binders for the new generation of interior materials] //Aviacionnye materialy i tehnologii. 2012. №S. S. 265–272.
    15. Sytyj Ju.V., Kisljakova V.I., Sagomonova V.A., Nikolaeva M.F. Novyj mnogoslojnyj uplotnitel'nyj material VTP-2P [The new multi-layer sealant VTP-2P] //Aviacionnye materialy i tehnologii. 2011. №4. S. 32–34.
    16. Sunil Jose T., Anoop Anand K. Joseph Rani. On the Mechanical Properties of EPDM/CIIR Blends Cured with Reactive Phenolic Resin //International Journal of Polymeric Materials. 2010. V. 59. №7. Р. 488–497.
    17. Xie Chan, Jia Zhixin, Jia Demin et al. The Effect of Dy (III) Complex with
    2-Mercaptobenzimidazole on the Thermo-Oxidation Aging Behavior of Natural Rubber Vulcanizates //International Journal of Polymeric Materials. 2010. V. 59. №9. Р. 663–679.
    18. Patel Hasmukh S., Patel Bhavdeep K., Morekar Manish M., Dixit Bharat C. Synthesis. Characterization and Glass Reinforcement of Urea-Formaldehyde-Phenol Resins //International Journal of Polymeric Materials. 2009. V. 58. №11. Р. 604–611.
    19. Yoganathan R.B., Mammucari R., Foster N.R. Dense Gas Processing of Polymers //Polymer Reviews. 2011. V. 50. №2. Р. 144–177.
    20. Bing Li, Qingfeng Wu, Nanqiao Zhou, Baoshan Shi. Batch Foam Processing of Polypropylene/Polydimethylsiloxane Blends //International Journal of Polymeric Materials. 2010. V. 60. №1. Р. 51‒61.
    21. Jorge R.M., Lopes L., Benzi M.R. et al. Thiol Addition to Natural Rubber: Effect on the Tensile and Thermal Properties //International Journal of Polymeric Materials. 2010. V. 59. №5.
    Р. 330–341.
    22. Seo J.H., Cha S.W., Kim H.B. Diffused Reflection of Microcellular Foamed Polycarbonate //Polym. Plastics Technol. Eng. 2009. V. 48. Р. 351–358.
    23. Neoh S.B., Azura A.R., Hashim A.S. Comparison of the Different Vulcanization Techniques of Styrene Modified Natural Rubber (SNR) as an Impact Modifier of Natural Rubber-Based High Impact Polystyrene (NRHIPS) //Polym. Plastics Technol. Eng. 2011. V. 49. Р. 121–126.

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