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Aviation materials and tecnologes №3, 2019

DOI: 10.18577/2071-9140-2019-0-3-3-8

UDC: 620.178.35

Pages: 3-8

V.V. Antipov1, M.V. Grigoryev1, A.N. Konovalov1, A.A. Meshkov2, N.Yu. Serebrennikova1

[1] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru
[2] Open Joint Stock Company «National Institute of Aviation Technologies», info@niat.ru

RESEARCH OF THE INFLUENCE OF RIVETING ON THE LOW-CYCLE FATIGUE OF RIVETED CONNECTION SHEETS OF ALUMINUM-LITHIUM ALLOYS

Riveted joints in the construction of aviation engineering occupy one of the main places among technological processes during the assembly of structural elements. Manufacturing technology of riveted joints is well-proven and a great deal of reference documentation is released. However, in this documentation there are not presented the most advanced materials, with characteristic features during the process of riveted connection with prework taken into account. The distinctive feature of 1441 and B-1481 alloys is additional requirements for manufacturing technology of riveted joints due to the alloys’ high rigidity and sensitivity to impact loads and constant stresses in the riveted seam under tension in the holes.

Keywords: Al–Li alloys, rivets of general application, rivets with compensator, press rivet, impact rivet, low-cycle fatigue.

Reference List

    1. Kablov E.N. Materialy novogo pokoleniya – osnova innovatsiy, tekhnologicheskogo liderstva i natsionalnoy bezopasnosti Rossii [Materials of the new generation – the basis of innovation, technological leadership and national security of Russia] // Intellekt & Tekhnologii. 2016. №2. S. 41–46.

    2. Kablov E.N. O nastoyashchem i budushchem VIAM i otechestvennogo materialovedeniya: intervyu [About the present and the future of the Institute of Scientific and Technical Information and Russian Materials Science: an interview] // Rossiyskaya akademiya nauk. 2015. 19 yanv. S. 10–15.

    3. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.

    4. Leshchiner L.N., Latushkina L.V., Fedorenko T.P. Splav 1441 sistemy Al–Cu–Mg–Li [Alloy 1441 of the Al–Cu–Mg–Li system] // Tez. dokl. Vsesoyuz. nauch. konf. «Metallovedeniye splavov alyuminiya s litiyem». M.: VILS, 1991. S. 76–77.

    5. Kablov E.N., Antipov V.V., Klochkova Yu.Yu. Alyuminiy-litiyevyye splavy novogo pokoleniya i sloistyye alyumostekloplastiki na ikh osnove [Aluminum-lithium alloys of a new generation and layered aluminum-glass plastics on their basis] // Tsvetnyye metally. 2016. №8 (884). S. 86–91.

    6. Zhegina I.P., Grigorenko V.B., Morozova L.V., Fomina M.A. Issledovaniye izmeneniya sostoyaniya poverkhnostnykh sloyev alyuminiylitiyevykh splavov 1441 i V-1469 pri kompleksnom vozdeystvii napryazheniy i korrozionno-aktivnoy sredy [Research of state changes of surface layers in aluminum – lithium alloys 1441 and V-1469 at a com-plex influence of stresses and corrosive environment] // Aviatsionnyye materialy i tekhnologii. 2014. №S4. S. 65–69. DOI: 10.18577/2071-9140-2014-0-s4-65-69.

    7. Oglodkov M.S., Grigorev M.V., Pakhomkin S.I., Ryabova E.N. Issledovaniye vliyaniya rezhimov gomogenizatsii na mekhanicheskiye svoystva krupnogabaritnykh slitkov iz alyuminiy-litiyevogo splava marki V-1481 [Research of influence of homogenizing modes on mechanical properties of large bars from aluminum-lithium alloys V-1481] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2017. №8 (56). St. 01. Available at: http://www.viam-works.ru (accessed: March 26, 2019). DOI: 10.18577/2307-6046-2017-0-8-1-1.

    8. Antipov V.V., Serebrennikova N.Yu., Nefedova Yu.N., Kozlova O.Yu., Panteleev M.D., Osipov N.N., Klychеv A.V. Tekhnologicheskie osobennosti Izgotovleniya detalej iz alyuminiy-litievogo splava 1441 [Manufacturing capability of Al–Li 1441 alloy details] // Trudy VIAM: elektron. nauch.-tekhnich. zhurn. 2018. №10 (70). St. 03 Available at: http://www.viam-works.ru (accessed: March 26, 2019). DOI: 10.18577/2307-6046- 2018-0-10-17-26.

    9. Karachevtsev F.N., Letov A.F., Protsenko O.M., Yakimova M.S. Razrabotka i primeneniye standartnykh obraztsov perspektivnykh splavov aviatsionnogo naznacheniya [Development and application of certified reference materials of airborne advanced alloys] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №10 (46). St. 08. Available at: http://www.viam-works.ru (accessed: March 26, 2019). DOI: 10.18577/2307-6046-2016-0-10-8-8.

    10. Morozova L.V., Ishodzhanova I.V. Issledovanie zakonomernostej izmeneniya relefa poverhnosti obrazcov iz alyuminij-litievyh splavov metodom lazernoj mikroskopii [Research of patterns of change of a relief of a surface of samples from aluminumlithium alloys a method of laser microscopy] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №10. St. 08. Available at: http://www.viam-works.ru (accessed: March 26, 2019). DOI: 10.18577/2307-6046-2014-0-10-8-8.

    11. Lukina E.A., Alekseyev A.A., Khokhlatova L.B. i dr. Fazovyye prevrashcheniya v protsesse dlitel'nykh temperaturnykh nagrevov dlya promyshlennykh splavov 1224, V-1469 i 1441 [Phase transformations in the process of long-term temperature heating for industrial alloys 1224, B-1469 and 1441] // Fizika metallov i metallovedeniye. 2011. №3. S. 253–261.

    12. Kablov E.N., Morozova L.V., Grigorenko V.B., Zhegina I.P., Fomina M.A. Issledovaniye vliyaniya korrozionnoy sredy na protsess nakopleniya povrezhdeniy i kharakter razrusheniya konstruktsionnykh alyuminiyevykh splavov 1441 i V-1469 pri ispytaniyakh na rastyazheniye i malotsiklovuyu ustalost [Investigation of the influence of the corrosive environment on the damage accumulation process and the nature of the destruction of structural aluminum alloys 1441 and B-1469 in tensile and low-cycle fatigue tests] // Materialovedeniye. 2017. №1. S. 41–48.

    13. Kablov E.N., Morozova L.V., Grigorenko V.B., Zhegina I.P., Fomina M.A. Study of the influence of a corrosive medium on the process of damage accumulation and the nature of failure of structural aluminum alloys 1441 and V-1469 under tensile and low-cycle fatigue testing // Inorganic Materials: Applied Research. 2017. Vol. 8. No. 4. P. 594–602.

    14. Grigorev M.V., Oglodkov M.S. Vliyaniye mekhanicheskoy obrabotki na mekhanicheskiye i ustalostnyye svoystva listov iz alyuminiy-litiyevykh splavov 1441 i V-1481 [Influence of machining on mechanical and fatigue properties of sheets from aluminum-lithium alloys 1441 and V-1481] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2018. №4 (64). St. 03. Available at: http://www.viam-works.ru (accessed: March 26, 2019). DOI: 10.18577/2307-6046-2018-0-4-20-27.

    15. Grinevich A.V., Rumyancev Yu.S., Morozova L.V., Terehin A.L. Issledovanie ustalostnoj dolgovechnosti alyuminievyh splavov 1163-T i V95o.ch.-T2 posle poverhnostnogo uprochneniya [Study of fatigue life of 1163-T and V95o.ch.-T2 aluminum alloys after surface hardening] // Aviacionnye materialy i tehnologii. 2014. №S4. S. 93–102. DOI: 10.18577/2071-9140-2014-s4-93-102.

    16. Gorbovets M.A., Kochetkov D.A., Khodinev I.A. Analiz i sravnenie rossijskogo i zarubezhnogo standartov, ustanavlivayushchikh metody ispytanij na termomekhanicheskuyu ustalost [The analysis and comparison of the RF and foreign standards for method of thermomechanical fatigue tests] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2017. №4. St. 11. Available at: http://www.viam-works.ru (accessed: March 26, 2019). DOI: 10.18577/2307-6046-2017-0-4-11-11.

    17. Belyaev M.S., Khvatskiy K.K., Gorbovets M.A. Sravnitelnyj analiz rossijskogo i zarubezhnyh standartov ispytanij na ustalost metallov [Comparative analysis of national standards of RF and the USA on methods of metals fatigue testing] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №9. St. 11. Available at: http://www.viam-works.ru (accessed: March 26, 2019). DOI: 10.18577/2307-6046-2014-0-9-11-11.

    18. Ospennikova O.G., Napriyenko S.A., Avtayev V.V. Vliyaniye morskoy vody na soprotivleniye mnogotsiklovoy ustalosti splava VT3-1 pri razlichnykh koeffitsiyentakh asimmetrii nagruzheniya [Boundary between single-crystal substrate and received by selective laser melting alloy ZhS32-VI structural and phase changes after high temperatures and tension influence investigation] // Trudy VIAM: elektron. nauch.-tekhnich. zhurn. 2019. №1 (73). St. 12. Available at: http://www.viam-works.ru (accessed: March 26, 2019). DOI: 10.18577/2307-6046-2019-0-1-115-124.

    19. Zolotorevskiy V.S. Mekhanicheskiye svoystva metallov [Mechanical properties of metals]. M.: Metallurgiya, 1983. S. 322–324.

Full version

DOI: 10.18577/2071-9140-2019-0-3-9-13

UDC: 669.018.29

Pages: 9-13

K.A. Udod1, N.N. Trofimenko1, D.N. Romanenko1, G.S. Sevalnev1

[1] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru

PROSPECTS FOR THE DEVELOPMENT OF CONSTRUCTIONAL ALUMINIUM-DOPED STEELS

The prospects for the development of new structural steels with increased aluminum content are considered. It is shown that research in this area is carried out both in Russia and abroad. It is determined that the main research and development line is to improve the processability of aluminum-containing steels due to their tendency to form brittle intermetallic compounds. The analysis of the development of steels with high aluminum content gives confidence that such materials can be successfully applied in the aircraft industry.

Keywords: aluminum, steel with aluminum, alloying with aluminum, high specific strength, corrosion resistance, strength, damping steel.

Reference List

    1. Antipov V.V., Chesnokov D.V., Kozlov I.A., Volkov I.A., Petrova A.P. Podgotovka poverkhnosti alyuminiyevogo splava V1469 pered primeneniyem v sostave sloistogo gibridnogo materiala [Surface preparation aluminum alloy V-1469 before use in the composition of layered hybrid material] // Trudy VIAM: elektron. nauch.-tekhnich. zhurn. 2018. №4 (64). St. 07. Available at: http://www.viam-works.ru (accessed: March 05, 2019). DOI: 10.18577/2307-6046-2018-0-4-59-65.

    2. Kablov E.N., Ospennikova O.G., Petrushin N.V., Visik E.M. Monokristallicheskij zharoprochnyj nikelevyj splav novogo pokoleniya s nizkoj plotnostyu [Single-crystal nickel-based superalloy of a new generation with low-density] // Aviacionnye materialy i tehnologii. 2015. №2 (35). S. 14–25. DOI: 10.18577/2071-9140-2015-0-2-14-25.

    3. Vahromov R.O., Tkachenko E.A., Popova O.I., Milevskaya T.V. Obobshhenie opyta primeneniya i optimizaciya tehnologii izgotovleniya polufabrikatov iz vysokoprochnogo alyuminievogo splava 1933 dlya silovyh konstrukcij sovremennoj aviacionnoj tehniki [Summarizing of the experience of usage and optimization of manufacturing technology semi-fished product of high strength aluminum alloy 1933 for the primary structures of modern aircraft] // Aviacionnye materialy i tehnologii. 2014. № 2. S. 34–39. DOI: 10.18577/2107-9140-2014-0-2-34-39

    4. Kablov E.N., Lukin V.I., Ospennikova O.G. Perspektivnyye alyuminiyevyye splavy i tekhnologii ikh soyedineniya dlya izdeliy aviakosmicheskoy tekhniki [Perspective aluminum alloys and technologies of their connection for aerospace products] // Tez. dokl. 2-oj Mezhdunar. konf. «Alyuminiy-21. Svarka i payka». SPb., 2012. St. 8.

    5. Kablov E.N., Ospennikova O.G., Lomberg B.S. Strategicheskiye napravleniya razvitiya konstruktsionnykh materialov i tekhnologiy ikh pererabotki dlya aviatsionnykh dvigateley nastoyashchego i budushchego [Strategic directions of development of structural materials and technologies for their processing for aviation engines of the present and the future] // Avtomaticheskaya svarka. 2013. №10. S. 23–32.

    6. Kablov E.N., Kashapov O.S., Pavlova T.V., Nochovnaya N.A. Razrabotka opytno-promyshlennoy tekhnologii izgotovleniya polufabrikatov iz psevdo-alfa-titanovogo splava VT41 [Development of an experimental-industrial technology for manufacturing semi-finished products from pseudo-alpha-titanium alloy VT41] // Titan. 2016. №2 (52). S. 33–42.

    7. Kablov E.N., Lukina E.A., Sbitneva S.V., Khokhlatova L.B., Zaytsev D.V. Formirovaniye metastabilnykh faz pri raspade tverdogo rastvora v protsesse iskusstvennogo stareniya Al-splavov [The formation of metastable phases during the decomposition of the solid solution in the process of artificial aging Al-alloys] // Tekhnologiya legkikh splavov. 2016. №3. S. 7–17.

    8. Panarin A.V., Ilin V.A. Alyuminirovanie konstruktsionnykh staley metodom termicheskogo razlozheniya metalloorganicheskoy zhidkosti [Aluminizing of structural steels by thermal decomposition of organometallic fluid] // Aviacionnye materialy i tehnologii. 2014. №1. S. 20–24. DOI: 10.18577/2071-9140-2014-0-1-20-24.

    9. Ulig G.G., Revi R.U. Korroziya i borba s ney. Vvedeniye v korrozionnuyu nauku i tekhniku [Corrosion and struggle with it. Introduction to corrosion science and technology]. L.: Khimiya, 1989. 456 s.

    10. Udelnyy ves stali [Specific weight of steel] // Promyshlennyy portal. Available at: http://promportal.su/stal13 (accessed: March 11, 2019).

    11. Frommeyer G., Brux U. Microstructures and Mechanical Properties of High-Strength Fe–Mn–Al–C Light-Weight TRIPLEX Steels // Steel Research International. 2006. Vol. 77. Р. 627–633.

    12. Chudakov I.B. Strukturnyye mekhanizmy formirovaniya vysokodempfiruyushchego sostoyaniya v ferromagnitnykh splavakh na osnove a-Fe: dis. … kand. fiz.-mat. nauk [Structural mechanisms for the formation of a high damping state in α-Fe-based ferromagnetic alloys: thesis, Cand. Sc. (Phys.&Math)]. M.: TSNIIchermet im. I.P. Bardina, 1994. 194 s.

    13. Diagrammy sostoyaniya dvoynykh metallicheskikh sistem: spravochnik / pod obshch. red. N.P. Lyakisheva [State diagrams of double metal systems: a handbook / ed. N.P. Lyakishev]. M.: Mashinostroyeniye, 1996. T. 1. 996 s.

    14. Liu C.T., Lee E.H., McKamey C.G. Anenvrionmental effect as the major cause for room-temperature embrittlement if iron-aluminum // Scripta Metallurgica. 1989. Vol. 23. Р. 875–880.

    15. Garcia-Alonso M.C., Lopez M.F., Escudero M.L. et al. Corrosion behaviour of an Fe3Al-type intermetallic in a chloride containing solution // Intermetallics. 1999. No. 7. Р. 185–191.

    16. Udod K.A. Upravleniye strukturoy korrozionnostoykikh staley martensitnogo, martensitno-austenitnogo i ferritnogo klassov dlya povysheniya mekhanicheskikh svoystv i korrozionnoy stoykosti: dis. … kand. tekhn. nauk [Control of the structure of corrosion-resistant steels of martensitic, martensitic-austenitic and ferritic classes to improve the mechanical properties and corrosion resistance: thesis, Cand. Sc. (Tech.)]. M.: TsNIIchermet im. I.P. Bardina, 2016. 161 s.

    17. Rodionova I.G., Stukalin S.V., Baklanova O.N., Udod K.A. i dr. Vliyaniye legirovaniya alyuminiyem i deformatsionno-termicheskoy obrabotki na kristallicheskoye stroyeniye prokata [Effect of aluminum doping and deformation-heat treatment on the crystalline structure of rolled metal] // Metallurg. 2016. №8. S. 67–71.

    18. Skvortsov A.I., Kondratov V.M. High-damping Cr–Al steel // Metal Science and Heat Treatment. 1991. Vol. 33. Issue 11. Р. 876–878.

    19. Chudakov I.B., Aleksandrova N.M., Makushev S.Yu. High-damping alloys and steels based on Fe–Al: structure, properties, and application features // Metal Science and Heat Treatment. 2012. Vol. 54. Issue 5–6. Р. 239–243.

    20. Chudakov I.B., Aleksandrova N.M., Makushev S.Yu. Peculiar features of the structure and operational properties of new economical, high-damping steels // Steel. 2007. Vol. 37. Issue 1. Р. 73–78.

Full version

DOI: 10.18577/2071-9140-2019-0-3-14-22

UDC: 669.717

Pages: 14-22

I. Benarieb1, L.B. Ber2, K.V. Antipov1, S.V. Sbitneva1

[1] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru
[2] Open Joint-Stock Company «All-Russia Institute of Light Alloys», info@oaovils.ru

TRENDS IN DEVELOPMENT OF WROUGHT ALLOYS OF Al–Mg–Si–(Cu) SYSTEM. Part 1 (review)

This article presents a national and foreign literature review for application of wrought aluminum alloys of Al–Mg–Si–(Cu) system 6ххх series. The practical significance of these materials in building industry and modern fields of machine building is shown. The classification of these alloys in dependence of content of the main alloying elements is proposed. Perspective domestic and foreign alloys for usage in transport engineering are considered. The main trends in development of these alloys in some branches of industry are formulated.

Keywords: wrought heat-treatable alloys of Al–Mg–Si–(Cu) system, 6ххх series aluminium alloys, perspective materials, weight efficiency.

Reference List

    1. Antipov V.V. Perspektivy razvitiya alyuminievyh, magnievyh i titanovyh splavov dlya izdelij aviacionno-kosmicheskoj tehniki [Prospects for development of aluminium, magnesium and titanium alloys for aerospace engineering] // Aviacionnye materialy i tehnologii. 2017. №S. S. 186–194. DOI: 10.18577/2107-9140-2017-0-S-186-194.

    2. Antipov V.V., Klochkova Yu.Yu., Romanenko V.A. Sovremennye alyuminievye i alyuminij-litievye splavy [Modern aluminum and aluminum-lithium alloys] // Aviacionnye materialy i tehnologii. 2017. №S. S. 195–211.

    3. Kablov E.N., Antipov V.V., Klochkova Yu.Yu. Alyuminiy-litiyevyye splavy novogo pokoleniya i sloistyye alyumostekloplastiki na ikh osnove [New-generation aluminum-lithium alloys and layered aluminum-glass-reinforced plastics based on them] // Tsvetnyye metally. 2016. №8. S. 86–91.

    4. Kolobnev N.I., Ber L.B., Khokhlatova L.B., Ryabov D.K. Struktura, svoystva i primeneniye splavov sistemy Al–Mg–Si–(Cu) [Structure, properties and application of alloys of the Al–Mg–Si–(Cu) system] // Metallovedeniye i termicheskaya obrabotka metallov. 2011. №9. S. 40–45.

    5. Proceedings of the 16th International Aluminum Alloys Conference (ICAA16). 2018. Available at: http://www.icaa-conference.net/ICAA16/ICAA16-TOC.html (accessed: March 22, 2019).

    6. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period to 2030] // Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.

    7. Fridlyander I.N. Sozdaniye, issledovaniye i primeneniye alyuminiyevykh splavov [Creation, research and application of aluminum alloys] // Izbrannyye trudy. M.: Nauka, 2013. 291 s.

    8. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.

    9. Duyunova V.A., Nechaykina T.A., Oglodkov M.S., Yakovlev A.L., Leonov A.A. Perspektivnyye razrabotki v oblasti legkikh materialov dlya sovremennoy aviakosmicheskoy tekhniki [Promising developments in the field of light materials for modern aerospace engineering] // Tekhnologiya legkikh splavov. 2018. №4. S. 28–43.

    10. Teleshov V.V., Zakharov V.V. Nauchno-tekhnicheskaya konferentsiya v FGUP «VIAM» [Scientific and technical conference at FSUE «VIAM»] // Tekhnologiya legkikh splavov. 2016. №3. S. 89–93.

    11. Teleshov V.V., Zakharov V.V. Konferentsiya v Alyuminiyevoy Assotsiatsii [Conference at the Aluminum Association] // Tekhnologiya legkikh splavov. 2017. №4. S. 115–116.

    12. Belov N.A., Antipov V.V., Kaybyshev R.O., Eskin D.G. Itogi mezhdunarodnoy konferentsii ICAA12 [The results of the international conference ICAA12] // Metallovedeniye i termicheskaya obrabotka metallov. 2011. №9. S. 3–5.

    13. Ovchinnikov V.V. Perspektivy razvitiya vysokotekhnologichnykh deformiruyemykh alyuminiyevykh splavov dlya svarnykh konstruktsiy. Chast 1 [Prospects for the development of high-tech wrought aluminum alloys for welded structures. Part 1] // Mashinostroyeniye i inzhenernoye obrazovaniye. 2017. №2. S. 24–38.

    14. Ovchinnikov V.V. Perspektivy razvitiya vysokotekhnologichnykh deformiruyemykh alyuminiyevykh splavov dlya svarnykh konstruktsiy. Chast 2 [Prospects for the development of high-tech wrought aluminum alloys for welded structures. Part 2] // Mashinostroyeniye i inzhenernoye obrazovaniye. 2017. №3. S. 22–39.

    15. Gureyeva M.A., Grushko O.E. Alyuminiyevyye splavy v svarnykh konstruktsiyakh sovremennykh transportnykh sredstv [Aluminum alloys in the welded structures of modern vehicles] // Mashinostroyeniye i inzhenernoye obrazovaniye. 2009. №3. S. 27–41.

    16. Polmear I. Wrought aluminium alloys // Light alloys: metallurgy of the light metals. Butterworth-Heinemann, 2017. P. 157–263.

    17. Mukhopadhyay P. Alloy designation, processing, and use of AA6xxx series aluminium alloys // ISRN Metallurgy. 2012. T. 2012. P. 1–15.

    18. Poznak A., Freiberg D., Sanders P. Automotive Wrought Aluminium Alloys // Fundamentals of Aluminium Metallurgy. 2018. P. 333–386. DOI: 10.1016/B978-0-08-102063-0.00010-2.

    19. Benedyk J.C. Aluminum alloys for lightweight automotive structures // Materials, design and manufacturing for lightweight vehicles. Woodhead Publishing, 2010. P. 79–113.

    20. Ng C.–H., Yahaya S.N.M., Majid A.A.A. Reviews on aluminium alloys series and its applicaions // Academia Journal of Scientific Research. 2017. No. 5 (12). P. 708–716.

    21. Rambabu P., Prasad N.E., Kutumbarao V.V., Wanhill R.J.H. Aluminium alloys for aerospace applications // Aerospace Materials and Material Technologies. Singapore: Springer, 2017. P. 29–52.

    22. Jawalkar C.S., Yashpal, Kant S. A Review on Use of Aluminium Alloys in Aircraft Components // i-Manager's Journal on Material Science. 2015. Vol. 3. No. 3. P. 33.

    23. Starke E.A., Staley J.T. Application of modern aluminium alloys to aircraft // Fundamentals of aluminium metallurgy. Woodhead Publishing, 2011. P. 747–783.

    24. Rajan R., Kah P., Mvola B., Martikainen J. Trends in aluminium alloy development and their joining methods // Reviews on Advanced Materials Science. 2016. Vol. 44. No. 4. P. 383–397.

    25. Belov N.A. Fazovyy sostav alyuminiyevykh splavov [Phase composition of aluminum alloys]. M.: MISiS, 2009. 392 s.

    26. EN 573-3:2013. Aluminium and aluminium alloys – Chemical composition and form of wrought products – Part 3: Chemical composition and form of propucts. European committee for standardization, 2013. 36 p.

    27. Aluminum Association. International alloy designations and chemical composition limits for wrought aluminum and wrought aluminum alloys // Teal Sheets. 2015. P. 1–31.

    28. Varga I.I., Furman I.D., Klepachevskaya S.Yu. Problemy osvoyeniya proizvodstva slitkov malolegirovannykh splavov sistemy Al–Mg–Si [Problems of mastering the production of ingots of low-alloy alloys of the Al–Mg–Si system] // Metallovedeniye, lit'ye i obrabotka splavov. M.: VILS, 1995. S. 139–146.

    29. Gorbunova T.V. Sravnitelnyy analiz trebovaniy otechestvennykh i zarubezhnykh standartov k produktsii iz splavov sistemy Al–Mg–Si [Problems of mastering the production of ingots of low-alloy alloys of the Al–Mg–Si system] // Tekhnologiya legkikh splavov. 1999. №1–2. S. 126–129.

    30. Kaufman J.G. Introduction to aluminum alloys and tempers. ASM international, 2000. 242 p.

    31. Songmene V., Kouam J., Zaghbani I. et al. Global Machinability of Al–Mg–Si Extrusions // Aluminium Alloys-New Trends in Fabrication and Applications «IntechOpen». 2012. P. 223–251.

    32. Kablov E.N. Tendentsii i oriyentiry innovatsionnogo razvitiya Rossii: sb. inform. materialov. 3-ye izd., pererab. i dop. [Trends and guidelines for the innovative development of Russia: collection of information materials. 3rd ed., rev. and add.]. M.: VIAM, 2015. 720 s.

    33. Makarov G.S. Tendentsii v primenenii produktsii iz alyuminiya i yego splavov v Rossii [Trends in the application of products from aluminum and its alloys in Russia] // Tsvetnyye metally. 2007. №5. S. 82–89.

    34. Makarov G.S., Kharitonovich A.M. Dostizheniya v proizvodstve press-izdeliy iz alyuminiyevykh splavov (po materialam mezhdunarodnogo seminara ET-2008) [Achievements in the production of press products from aluminum alloys (based on materials from the international seminar ET-2008)] // Tekhnologiya legkikh splavov. 2008. №4. S. 99–112.

    35. Makarov G.S. Metallurgicheskiye osobennosti proizvodstva slitkov iz Al–Mg–Si-splavov dlya pressovaniya [Metallurgical features of the production of ingots from Al–Mg–Si alloys for pressing] // Tekhnologiya legkikh splavov. 2011. №1. S. 41–63.

    36. Berezhnoy V.L. Tekhnologicheskiye printsipy postroyeniya mnogotselevoy potochnoy linii dlya proizvodstva konstruktsionnykh press-izdeliy [Technological principles for constructing a multi-purpose production line for the production of structural press products] // Tekhnologiya legkikh splavov. 2008. №4. S. 53–65.

    37. Fridlyander I.N., Sister V.G., Grushko O.E. i dr. Alyuminiyevyye splavy – perspektivnyy material v avtomobilestroyenii [Aluminum alloys – a promising material in the automotive industry] // Metallovedeniye i termicheskaya obrabotka metallov. 2002. №9. S. 3–9.

    38. Kablov E.N., Grushko O.E., Grinevich A.V. «Letayushchiy metall» – v avtomobilestroyenie [«Flying metal» to the automotive industry]. 2005. Available at: http://viam.ru/public/files/2005/2005-204333 (accessed: September 15, 2018).

    39. Zheng K., Politis D.J., Wang L., Lin J. A review on forming techniques for manufacturing lightweight complex–shaped aluminium panel components // International Journal of Lightweight Materials and Manufacture. 2018. Vol. 1. No. 2. Р. 55–80.

    40. Bloeck M. Aluminium sheet for automotive applications // Advanced Materials in Automotive Engineering. Woodhead Publishing, 2012. Р. 85–108.

    41. Mohamed M.S., Ismail A. Review on sheet metal forming process of aluminium alloys // 17th International Conference on Applied Mechanics and Mechanical Engineering. 2016. Р. 129–141.

    42. Chertovikov V.M. O podgotovke proizvodstva polufabrikatov iz alyuminiyevykh splavov dlya relsovogo transporta [About preparation of the production of semi-finished products from aluminum alloys for rail transport] // Perspektivnyye tekhnologii legkikh i spetsialnykh splavov. M.: Fizmatlit, 2006. S. 409–414.

    43. Davydov V.G., Zakharov V.V., Sinyavskiy V.S. et al. Vybor sostava i tekhnologii polucheniya listov iz splava Al–Mg–Si–Cu [The choice of composition and technology for producing sheets from Al–Mg–Si Cu alloy] // Tekhnologiya legkikh splavov. 2002. №4. S. 38–42.

    44. Kuznetsov A.O., Oglodkov M.S., Klimkina A.A. Vliyaniye khimicheskogo sostava na strukturu i svoystva splava sistemy Al–Mg–Si [The influence of chemical composition on structure and properties of Al–Mg–Si alloy] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2018. №7 (67). St. 01. Available at: http://www.viam-works.ru (accessed: September 15, 2018). DOI: 10.18577/2307-6046-2018-0-7-3-9.

    45. Klochkov G.G., Klochkova Yu.Yu., Romanenko V.A. Vliyanie temperatury deformacii na strukturu i svojstva pressovannyh profilej splava V-1341 sistemy Al–Mg–Si [Influence of deformation temperature on structure and properties of extruded products of Al–Mg–Si alloy V-1341] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №9. St. 01. Available at: http://www.viam-works.ru (accessed: February 15, 2018). DOI: 10.18577/2307-6046-2016-0-9-1-1.

    46. Voronov S.M. Protsessy uprochneniya splavov alyuminiy-magniy-kremniy i ikh novyye promyshlennyye kompozitsii [Hardening processes of aluminum-magnesium-silicon alloys and their new industrial compositions]. M.: Oborongiz, 1946. 152 s.

    47. Smith B. The Boeing 777 // Advanced Materials & Processes. 2003. Vol. 161. No. 9. P. 41–44.

    48. Fridez D., Lyu D. Novyye izdeliya iz alyuminiyevykh splavov dlya aerobusa A380 [New products from aluminum alloys for the A380 airbus] // Tsvetnyye metally. 2005. №8. S. 91–94.

    49. Lequeu P., Lassince P., Warner T. Aluminum alloy development: For the airbus A380. Part 2 // Advanced Materials & Processes. 2007. Vol. 165. No. 7. P. 41–44.

    50. Rendigs K.H. Airbus and current aircrafts metal technologies. Bremen: Airbus Germany, 2008. 60 p.

    51. Wanhill R.J.H. Aerospace applications of aluminum-lithium alloys // Aluminum-lithium Alloys. Butterworth-Heinemann. Elsevier, 2014. P. 503–535.

    52. GOST 4784–97. Alyuminiy i splavy alyuminiyevyye deformiruyemyye. Marki. M.: Standartinform, 2009. 32 s.

    53. Berezhnoy V.L. Rossiyskaya tekhnologiya i proizvodstvo press-izdeliy iz alyuminiyevykh splavov: mezhdu proshlym i budushchim [Russian technology and production of aluminum alloy press products: between the past and the future] // Tekhnologiya legkikh splavov. 2004. №3. S. 49.

    54. Konkevich V.Yu., Gogin V.B. Sovremennoye sostoyaniye alyuminiyevogo zagotovitelnogo litya i zadachi yego razvitiya [The current state of aluminum blank casting and the tasks of its development] // Tekhnologiya legkikh splavov. 2005. №1–4. S. 88–93.

    55. Mikhaylov E.D., Ivanova L.I. Perspektivy razvitiya pressovogo proizvodstva alyuminiyevykh splavov v Rossii [Prospects for the development of press production of aluminum alloys in Russia] // Tekhnologiya legkikh splavov. 2009. №2. S. 32–39.

    56. Berezhnoy V.L. O nekotoroy aktualnoy nauchnoy problematike v OMD [About some actual scientific problems in pressure metal treatment] // Tekhnologiya legkikh splavov. 2013. №3. S. 101–103.

    57. Berezhnoy V.L. O printsipakh formirovaniya tekhnologicheski mnogofunktsionalnoy sistemy ekstruzionnoy industrii v formate yeye razvitiya [On the principles of the formation of a technologically multifunctional system of the extrusion industry in the format of its development] // Tekhnologiya legkikh splavov. 2017. №4. S. 74–80.

    58. Makarov G.S. Aktualnye problemy retsiklinga alyuminiya v Rossii [Actual problems of aluminum recycling in Russia] // Tekhnologiya legkikh splavov. 2018. №4. S. 113–119.

    59. Splav na osnove alyuminiya i izdeliye, vypolnennoye iz nego: pat. 2215055 Ros. Federatsiya. №2001133680 [Alloy based on aluminum and a product made of it: pat. 2215055 Rus. Federation. No. 20011133680]; zayavl. 17.12.01; opubl. 27.10.03.

    60. Deformiruyemyy splav na osnove alyuminiya i izdeliye, vypolnennoye iz etogo splava: pat. 2255133 Ros. Federatsiya. №2003136632 [A deformable alloy based on aluminum and a product made of this alloy: pat. 2255133 Rus. Federation. No. 2003136632]; zayavl. 19.12.03; opubl. 27.06.05.

    61. Kolobnev N.I., Khokhlatova L.B., Ovsyannikov B.V. i dr. Osvoyeniye proizvodstva polufabrikatov iz korrozionnostoykogo svarivayemogo splava marki 1370 sistemy Al–Mg–Si–Cu [Development of the production of semi-finished products from a corrosion-resistant welded alloy of grade 1370 of the Al–Mg–Si–Cu system] // Tekhnologiya legkikh splavov. 2002. №4. S. 44–47.

    62. Kolobnev N.I., Khokhlatova L.B., Samokhvalov S.V. Splav 1370 sistemy Al–Mg–Si–Cu [Alloy 1370 of the Al–Mg–Si–Cu system] // 75 let. Aviatsionnyye materialy. Izbrannyye trudy «VIAM» 1932–2007 / pod obshch. red. E.N. Kablova. M.: VIAM, 2007. S. 177–179.

    63. Istoriya aviatsionnogo materialovedeniya. VIAM – 80 let: gody i lyudi / pod obshch. red. E.N. Kablova [History of aviation materials science. VIAM – 80 years: years and people / gen. ed. E.N. Kablov]. M.: VIAM, 2012. 520 s.

    64. Kolobnev N.I., Makhsidov V.V., Samokhvalov S.V., Dammer V.Kh., Kirillov V.A. Termomekhanicheskaya obrabotka splava 1370 pri izgotovlenii katanykh polufabrikatov i germetichnykh korpusov giroskopicheskikh ustroystv [Thermomechanical processing of alloy 1370 in the manufacture of rolled semi-finished products and sealed cases of gyroscopic devices] // Tekhnologiya legkikh splavov. 2016. №1. S. 57–61.

    65. Klochkov G.G., Grushko O.E., Popov V.I., Ovchinnikov V.V., Shamraj V.F. Struktura, tehnologicheskie svojstva i svarivaemost listov iz splava V-1341 sistemy Al–Mg–Si [Structure, technological properties and bondability of sheets from alloy V-1341 of Al–Mg–Si system] // Aviacionnye materialy i tehnologii. 2011. №1. S. 3–8.

    66. Klochkov G.G., Ovchinnikov V.V., Klochkova Yu.Yu., Romanenko V.A. Struktura i svojstva listov iz vysokotekhnologichnogo splava V-1341 sistemy Al–Mg–Si [Structure and properties of sheets from workable aluminium alloy V-1341 of Al–Mg–Si system] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2017. №12. St. 03. Available at: http://www.viam-works.ru (accessed: February 15, 2018). DOI: 10.18577/2307-6046-2017-0-12-3-3.

    67. Klochkov G.G., Grushko O.E., Ovchinnikov V.V., Popov V.I. Promyshlennoye osvoyeniye vysokotekhnologichnogo splava V-1341 sistemy Al–Mg–Si, legirovannogo kaltsiyem [Industrial development of hi-tech alloy V-1341 of the Al–Mg–Si system alloyed by calcium] // Metallovedeniye i termicheskaya obrabotka metallov. 2015. №1. S. 8–11.

Full version

DOI: 10.18577/2071-9140-2019-0-3-23-30

UDC: 678.7

Pages: 23-30

S.N. Semenova1, A.M. Chaykun1, R.R. Suleymanov1

[1] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru

ETHYLENE-PROPYLENE-DIENE RUBBER AND ITS USE IN RUBBER MATERIALS FOR SPECIAL PURPOSES (review)

The article contains a literature and patent review of the use of ethylene-propylene-diene rubbers in rubber materials for special purposes. The properties of rubbers and their vulcanizates are shown, the main manufacturers in the world market are listed. Methods and techniques for the preparation of rubber mixtures based on ethylene-propylene-diene rubbers are presented, including their compatibility with other rubbers and optimal vulcanization conditions. It is concluded that there is a great potential for using ethylene-propylene-diene rubbers in the development of materials with desired properties.

Keywords: rubbers, ethylene-propylene-diene rubber, heat resistance, ozone resistance, compatibility, compatibilizer, vulcanization.

Reference List

    1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
    2. Kablov E.N. Materialy novogo pokoleniya – osnova innovatsiy, tekhnologicheskogo liderstva i natsionalnoy bezopasnosti Rossii [Materials of a new generation - the basis of innovation, technological leadership and national security of Russia] // Intellekt i tekhnologiya. 2016. №2 (14). S. 16–21.
    3. Kablov E.N., Startsev V.O. Sistemnyj analiz vliyaniya klimata na mekhanicheskie svojstva polimernykh kompozitsionnykh materialov po dannym otechestvennykh i zarubezhnykh istochnikov (obzor) [Systematical analysis of the climatics influence on  mechanical  properties of the polymer composite materials based on domestic and foreign sources (review)] // Aviacionnye materialy i tehnologii. 2018. №2 (51). S. 47–58. DOI: 10.18577/2071-9140-2018-0-2-47-58.
    4. Kablov E.N. Materialy i khimicheskiye tekhnologii dlya aviatsionnoy tekhniki [Materials and chemical technologies for aviation technology] // Vestnik Rossiyskoy akademii nauk. 2012. T. 82. №6. S. 520–530.
    5. Kablov E.N. Rol khimii v sozdanii materialov novogo pokoleniya dlya slozhnykh tekhnicheskikh sistem [The role of chemistry in the creation of new generation materials for complex technical systems] // Tez. dokl. XX Mendeleyevskogo sezda po obshchey i prikladnoy khimii. Ekaterinburg: UrO RAN, 2016. S. 25–26.
    6. Laptev A.B., Barbotko S.L., Nikolaev E.V. Osnovnye napravleniya issledovanij sokhranyaemosti svojstv materialov pod vozdejstviem klimaticheskikh i ekspluatatsionnykh faktorov [The main research areas of the persistence properties of materials under the influence of climatic and operational factors] // Aviacionnye materialy i tehnologii. 2017. №S. S. 547–561. DOI: 10.18577/2071-9140-2017-0-S-547-561.
    7. Gryaznov V.I., Petrova G.N., Yurkov G.Yu., Buznik V.M. Smesevye termojelastoplasty so specialnymi svojstvami [Thermoplastic mixtures with special properties] // Aviacionnye materialy i tehnologii. 2014. №1. S. 25–29. DOI: 10.18577/2071-9140-2014-0-1-25-29.
    8. Eliseev O.A., Krasnov L.L., Zajceva E.I., Savenkova A.V. Razrabotka i modificirovanie elastomernyh materialov dlya primeneniya vo vseklimaticheskih usloviyah [Development and modifying of elastomeric materials for application in all weather conditions] // Aviacionnye materialy i tehnologii. 2012. №S. S. 309–314.
    9. Efimov V.A., Shvedkova A.K., Korenkova T.G., Kirillov V.N. Issledovanie polimernyh konstrukcionnyh materialov pri vozdejstvii klimaticheskih faktorov i nagruzok v laboratornyh i naturnyh usloviyah [Research of polymeric constructional materials at influence of climatic factors and loadings in laboratory and natural conditions] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №1. St. 05. Available at: http://viam-works.ru (accessed: April 04, 2019).
    10. Niels van der Aar. Introduction Lanxess. Available at: http://www.vizl.eu/cms/uploads/files/d9570e623d578b72267b0f6d29810d6f.pdf (accessed: April 08, 2019).
    11. Sealing Elements-Technical Handbook O-rings. The Netherlands Eriks, 2018. 256 p.
    12. Jana R.N., Nando G.B. Compatibilized Blends of Low Density Polyethylene and Poly Dimethyl Siloxane Rubber: Part I: Acid and Alkali Resistance Properties // Journal of Elastomer and Plastics. 2002. No. 34 (4). С. 349–363.
    13. Jalbert R.L. Modern Plastics Encyclopedia. New-York: McGraw-Hill, 1984. 841 p.
    14. Abou-Helal M.O., El-Sabbagh S.H. A Study on the Compatibility of NR-EPDM Blends Using Electrical and Mechanical Techniques // Journal of Elastomer and Plastics. 2005. No. 37 (10). P. 319–346.
    15. Compatibilization of dissimilar elastomer blends using ethylene/acrylate/acrylic acid terpolymers: pat. US 5281651A. No. 19920827772; filed 29.01.92; publ. 29.01.12.
    16. Compatibilization of elastomer blends: pat. US 5352739A. No. 19920972652; filed 06.11.92; publ. 06.11.12.
    17. Compatibilization of polar and nonpolar elastomer blends using functionalized ethylene/propylene copolymers or ethylene/propylene/diene terpolymers: pat. WO 1995002011A1 OMPI. No. 1993US06411; filed 07.07.93; publ. 19.01.95.
    18. EPDM rubber composition: pat. US 5985970A. No. 19960688827; filed 31.07.96; publ. 16.11.99.
    19. Vulcanizable EPDM rubber mixtures: pat. DE 4236218C2. No. 19924236218; filed 27.10.92; publ. 24.06.93.
    20. Сo-curing of NR/EPDM rubber blends: pat. US 4931508A. No. 19890418232; filed 16.11.89; publ. 05.06.90.
    21. Ethylene-propylene-diene rubber, elastomer composition and vulcanized rubber thereof: pat. US 5242971A. No. 19910689930; filed 05.10.90; publ. 07.09.93.
    22. Making rubber blends of diene rubber & EPR or EPDM: pat. US 4687810A. No. 19860815495; filed 02.01.86; publ. 18.08.87.
    23. Aging-resistant and low-temperature-resistant EPDM (ethylene-propylene-diene monomer) rubber cable material: pat. CN 104610663A. No. 20151021562; filed 15.01.15; publ. 13.05.15.
    24. Preparation of rubber composition comprised of EPDM/polyisoprene rubber blends and tire with sidewall comprised thereof: pat. US 7423089B2. No. 20050249866; filed 13.10.05; publ. 19.04.07.
    25. High-temperature-resistant material used for fireproof cable: pat. CN 108164836A. No. 201711209242; filed 27.11.17; publ. 15.06.18.
    26. Fluororubber/ethylene propylene diene monomer (EPDM) sealing material: pat. CN 108164886A. No. 201611117996; filed 07.12.16; publ. 15.06.18.
    27. Peroxide curable butyl formulations for rubber articles: pat. US 20060122317A. No. 20040005174; filed 06.12.04; publ. 08.06.06.
    28. Silicon rubber and EPDM mixed rubber and preparation method thereof: pat. CN 102061038A. No. 201010594134; filed 18.10.10; publ. 18.05.11.
    29. Silicon rubber/ethylene propylene terpolymer blending material and processing method: pat. CN 102775686A. No.  20121233193; filed 06.07.12; publ. 14.11.12.
    30. EPDM rubber: pat. CN 107057195A. No. 201611208144; filed 23.12.2016; publ. 18.08.2017.
    31. Ethylene propylene rubber material for sealing part of automobile heat dissipation system and production method of ethylene propylene rubber material: pat. CN 107090133A. No. 201710492764; filed 23.06.17; publ. 25.08.17.
    32. Nitrile rubber is used for low temperature seal of ozone / EPDM: pat. CN 102260380A. No. 20111189885; filed 07.07.11; publ. 30.11.11.
    33. Rubber compound for car engine mount enhanced dynamic characteristics by mixing epdm with silica: pat. KR 101280838B1. No. 20110043756; filed 11.05.11; publ. 21.11.12.
    34. Silicon rubber-ethylene propylene diene monomer (EPDM) rubber blend thermal conductive composite material and preparation method thereof: pat. CN 101817981A. No. 20101180632; filed 21.05.10; publ. 01.09.10.

Full version

DOI: 10.18577/2071-9140-2019-0-3-31-40

UDC: 678.6

Pages: 31-40

A.I. Tkachuk1, I.V. Terekhov1, Ya.M. Gurevich1, K.N. Grigoreva1

[1] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru

RESEARCH OF THE INFLUENCE OF THE MODIFYING ADDITIVES NATURE ON THE RHEOLOGICAL AND THERMOMECHANICAL PROPERTIES OF A PHOTOPOLYMER COMPOSITION BASED ON EPOXY VINYL ESTER RESIN

The article has investigated the physical-chemical, thermomechanical, and elastic-strength characteristics of samples of a modified epoxy vinyl ester resin, cured under the influence of incoherent UV radiation, with and without subsequent curing in a drying oven. Hexamethylene diisocyanate and diallyl phthalate were used as modifying additives. Using the DSC method, it has been determined that incoherent UV radiation does not allow reaching 99% of the conversion degree in the curable composition, therefore, in order to increase the heat-resistant and mechanical properties, it is necessary to additionally postcure polymer photocompositions. It has been also determined that modification of the epoxy vinyl ester resin leads to an increase in the glass transition temperature and the elastic strength properties of the cured samples.

Keywords: photopolymerization, epoxy vinyl ester resins, UV curing, isocyanates, infrared spectra, thermomechanical and elastic-strength characteristics.

Reference List

    1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
    2. Kablov E.N. Materialy novogo pokoleniya – osnova innovatsiy, tekhnologicheskogo liderstva i natsionalnoy bezopasnosti Rossii [Materials of a new generation - the basis of innovation, technological leadership and national security of Russia] // Intellekt i tekhnologii. 2016. №2. S. 16–22.
    3. Kablov E.N. Klyuchevaya problema – materialy [The key problem is materials] // Tendentsii i orientiry innovatsionnogo razvitiya Rossii. M.: VIAM, 2015. P. 458–464.
    4. Mishkin S.I., Raskutin A.E., Evdokimov A.A., Gulyaev I.N. Tehnologii i osnovnye etapy stroitelstva pervogo v Rossii arochnogo mosta iz kompozicionnyh materialov [Technologies and the main stages of construction of the arch bridge first in Russia from composite materials] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2017. №6 (54). St. 05. Available at: http://www.viam-works.ru (accessed: June 5, 2018). DOI: 10.18577/2307-6046-2017-0-6-5-5.
    5. Method and apparatus for UV curing thick pigmented coatings: pat. US5300331A; filed 19.02.94; publ. 05.04.94.
    6. UV-curing printing inks: pat. US4056453A; filed 29.07.76; publ. 01.11.77.
    7. UV-curable and non-volatile pigmented coatings: pat. US5747115A; filed 28.02.95; publ. 05.05.98.
    8. Evstrapov A.A., Lukashenko T.A., Tupik A.N. Primeneniye fotootverzhdayemykh opticheskikh kleyev dlya germetizatsii analiticheskikh mikrochipov [The use of photocurable optical adhesives for sealing analytical microchips ] // Nauchnoye priborostroyeniye. 2010. №1. S. 29–38.
    9. Naumov V.A. Vvedeniye v kinetiku fotoinitsiiruyemoy radikal'noy polimerizatsii UF lakov i krasok [Introduction to the kinetics of photoinitiated radical polymerization of UV varnishes and paints]. M.: MGUP, 2004. 165 s.
    10. Yagci Y., Jokusch S., Turro N.J. Photoinitiated Polymerization: advances, challenges, and opportunities // Macromolecules. 2010. Vol. 43. P. 6245–6250.
    11. Anastas P.T., Warner J.C. Green Chemistry: Theory and Practice. N.-Y.: Oxford University Press, 1998. 148 p.
    12. Jennise T.T.T., Yuhazri M.Y., Sihombing H. et. al. Gravity Effects of Curing Angle on Laminated Composite Structures: a Review on Novel Study // Advances in Materials Science and Engineering. 2013. Vol. 2013. Article ID 876824. DOI: 10.1155/2013/876824.
    13. Wang Z., Khaliulin V., Kovalev V., Khamidullin O. Material properties and mold folded core based on ultra-violet cured resins // Transactions of Nanjing University of Aeronautics and Astronautics. 2016. Issue 5. P. 529–535.
    14. Esnaola A., Ulacia I., Elguezabal B. et al. Design, manufacturing and evaluation of glass/polyester composite crash structures for lightweight vehicles A // International Journal of Automotive Technology. 2016. Vol. 17. P. 1013-22. DOI: 10.1007/s12239.
    15. Tena I., Esnaola A., Sarrionandia M. et al. Out of die ultraviolet cured pultrusion for automotive crash structures // Composites. Part B: Engineering. 2015. Vol. 79. P. 209–216. DOI: 10.1016/j.compositesb.2015.04.044.
    16. Gauthier C., Galy J., Ech-Cherif El-Kettani M. et al. Evaluation of epoxy crosslinking using ultrasonic Lamb waves // International Journal of Adhesion and Adhesives. 2018. Vol. 80 P. 1–6. DOI: 10.1016/j.ijadhadh.2017.09.008.
    17. Xiaohui Zhang, Yugang Duan, Xinming Zhao, Dichen Li. UV stepwise cured fabrication of glass fiber/acrylate composites: Effects of exposure dose on curing uniformity and interlaminar shear strength // Journal of Composite Materials. 2016. Vol. 50. Issue 10. P. 1395–1401. DOI: 10.1177/0021998315592004.
    18. Tena I., Sarrionandia M., Torre J., Aurrekoetxea J. The effect of process parameters on ultraviolet cured out of die bent pultrusion process // Composites. Part B: Engineering. 2016. Vol. 89. P. 9–17. DOI: 10.1016/j.compositesb.2015.11.027.
    19. Domínguez I.S., Tena I., Sarrionandia M., Torre J. Effect of ultraviolet curing kinetics on the mechanical properties of out of die pultruded vinyl ester composites // Composites. Part A: Applied Science and Manufacturing. 2018. Vol. 109. P. 280–289. DOI: 10.1016/j.compositesa.2018.03.015.
    20. Jaswal S., Gaur B. New trends in vinyl ester resins // Reviews in Chemical Engineering. 2014. Vol. 30. P. 567–581.
    21. Roberts K.N., Simon G.P., Cook W.D., Burchill P.J. Cure and rubber toughening of vinyl ester resins in Advanced Polymeric materials: structure property relationship. Boca Raton FL USA: CRC Press. 2004. P. 235–270.
    22. Yagci Y., Jokusch S., Turro N.J. Photoinitiated Polymerization: advances, challenges, and opportunities // Macromolecules. 2010. Vol. 43. P. 6245–6250.
    23. Bagdasaryan Kh.S. Teoriya radikalnoy polimerizatsii [Theory of radical polymerization]. M.: Akademii nauk SSSR, 1959. 297 s.
    24. Tsybin A.I., Tkachuk A.I., Grebeneva T.A., Samatadze A.I., Novikov M.M. Issledovaniye ekspluatatsionnykh svoystv oligoefirakrilatnogo svyazuyushchego, otverzhdennogo pod vozdeystviyem kogerentnogo UF-izlucheniya [Investigation of the operational properties of an oligoester acrylate binder cured under the influence of coherent UV radiation] // Klei. Germetiki. Tekhnologii. 2016. №6. S. 13–19.
    25. Karl Fink J. Reactive polymers fundamentals and applications. William Andrew Publishing, 2005. 780 p.
    26. Seyhan A., Gojny F.H., Tanglu M., Schulte K. Critical aspects related to processing of carbon nanotube/unsaturated thermoset polyester nanocomposites // European Polymer Journal. 2007. Vol. 43. P. 374–379. DOI: 10.1016/j.eurpolymj.2006.11.018.
    27. Chen Yanyan, Marakhovskij P.S., Malysheva G.V. Opredelenie teplofizicheskikh svojstv epoksidnykh materialov v protsesse ikh otverzhdeniya [Determination of thermophysical properties of epoxy materials during their curing] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2018. №9 (69). St. 12. Available at: http://www.viam-works.ru (accessed: June 05, 2019). DOI: 10.18577/2307-6046-2018-0-9-119-123.
    28. Malysheva G.V., Guzeva T.A., Grashchenkov D.V., Raskutin A.E. Vliyaniye tekhnologii nagreva na prodolzhitelnost protsessa otverzhdeniya polimernykh kompozitsionnykh materialov [The influence of heating  technology on the duration  of the curing process of polymer composite materials] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2018. №8 (68). St. 02. Available at: http://www.viam-works.ru (accessed: June 05, 2019). DOI: 10.18577/2307-6046-2018-0-2-23-27.
    29. Zhao Peizhong, Hu Fangyou, Huang Xuren. Composite repair to aluminum alloy plate by photoinitiated and thermal curing // Journal of Composite Materials. 2013. Vol. 47. Issue 9. P. 1179–1184. DOI: 10.1177/0021998312446183.
    30. Polyurethane vinyl ethers: pat. US5200490A; filed 23.03.1991; publ. 06.04.1993.
    31. Guseva M.A. Ispolzovaniye reologicheskogo metoda ispytaniy pri razrabotke polimernykh materialov razlichnogo naznacheniya [The use of the rheological tests in the development of polymeric materials for various purposes] // Trudy VIAM: elektron. nauch.-tekhnich. zhurn. 2018. №11 (71). St. 05. Available at: http://www.viam-works.ru (accessed: June 05, 2019). DOI: 10.18577/2307-6046-2018-0-11-35-44.

Full version

DOI: 10.18577/2071-9140-2019-0-3-41-47

UDC: 678.8

Pages: 41-47

V.M. Gurenkov1, V.О. Gorshkov1, V.P. Chebotarev1, Т.N. Prudskova1, Т.I. Andreeva1

[1] Joint Stock Company «Institute of plastics named after G.S. Petrov», dir@instplast.ru

COMPARATIVE ANALYSIS OF PROPERTIES OF POLYETHERETHERKETONE OF DOMESTIC AND FOREIGN PRODUCTION

The article is devoted to the problem of import substitution of high-temperature constructional thermoplastics. The results of the study of the properties of polyetheretherketone domestic (Institute of plastics) and foreign (Victrex) production. The current state of Russian production of polyether ether ketone is discussed.
Developed a basic branded assortment of products that meet the assortment of foreign manufacturers.

Keywords: thermoplastics, polyetheretherketone, additive technologies, import substitution.

Reference List

    1. Polyether ketone and method of producing the same: pat. US7217780B2; filed 10.12.02; publ. 21.04.05.

    2. Maiti S., Mandal B.K. Aromatic polyethers by nucleophilic displacement polymerization // Progress in Polymer Science. 1986. Vol. 12. No. 1–2. P. 111–153.

    3. Kirin B.S., Kuznetsova K.R., Petrova G.N., Sorokin A.E. Sravnitelnyy analiz svoystv poliefirefirketonov otechestvennogo i zarubezhnogo proizvodstva [Comparative analysis of properties of polyetheretherketones of domestic and foreign production] // Trudy VIAM: elektron. nauch.-tekhnich. zhurn. 2018. №5 (65). St. 05. Available at: http://viam-works.ru (accessed: July 28, 2019). DOI: 10.18577/2307-6046-2018-0-5-34-43.

    4. Moon G.Y., Rhim J.W. Sulfonated peek ion exchange membranes for direct methanol fuel cell applications // Macromolecular research. 2007. Vol. 15. No. 4. R. 379–384.

    5. Williams D.F., McNamara A., Turner R.M. Potential of polyetheretherketone (PEEK) and carbon-fibre-reinforced PEEK in medical applications //Journal of materials science letters. 1987. Vol. 6. No. 2. P. 188–190.

    6. Ha S.-W., Hauert R., Ernst K.-H., Wintermantel E. Surface analysis of chemically-etched and plasma-treated polyetheretherketone (PEEK) for biomedical applications // Surface and coatings technology. 1997. Vol. 96. No. 2–3. P. 293–299.

    7. Davim J.P., Reis P., Lapa V., Antonio C.C. Machinability study on polyetheretherketone (PEEK) unreinforced and reinforced (GF30) for applications in structural components // Composite Structures. 2003. Vol. 62. No. 1. P. 67–73.

    8. Normand B., Takenouti H., Keddam M. et al. Electrochemical impedance spectroscopy and dielectric properties of polymer: application to PEEK thermally sprayed coating // Electrochimica Acta. 2004. Vol. 49. No. 17–18. P. 2981–2986.

    9. Sposob polucheniya poliefirketona: pat. 2673242 Ros. Federatsiya [The method of producing polyetherketone: pat. 2673242 Rus. Federation]; zayavl. 27.06.18; opubl. 23.11.18.

    10. Kalinchev E.L., Sakovtseva M.B. Svoystva i pererabotka termoplastov: sprav. Posobiye [Properties and processing of thermoplastics: ref. allowance]. L.: Khimiya, 1983. S. 36.

    11. Kruth J.-P., Levy G., Klocke F., Childs T.H.C. Consolidation phenomena in laser and powder-bed based layered manufacturing // Annals of the CIRP. 2007. Vol. 56. No. 2. P. 730–759.

    12. Bikas H., Stavropoulos P., Chryssolouris G. Additive manufacturing methods and modeling approaches: a critical review // International Journal of Advanced Manufacturing Technology. 2016. Vol. 83. P. 389–405.

    13. Hill N., Haghi M. Deposition direction-dependent failure criteria for fused deposition modeling polycarbonate // Rapid Prototyping Journal. 2014. Vol. 20. No. 3. P. 221–227.

    14. Novakova-Marcincinova L., Kuric I. Basic and Advanced Materials for Fused Deposition Modeling Rapid Prototyping Technology // Manufacturing and Industrial Engineering. 2012. Vol. 11 (1). P. 24–27.

    15. Goodridge R.D., Tuck C.J., Hague R.J.M. Laser sintering of polyamides and other polymers // Progress in Materials Science. 2012. Vol. 57. P. 229–267.

Full version

DOI: 10.18577/2071-9140-2019-0-3-48-58

UDC: 667.621

Pages: 48-58

R.R. Mukhametov1, A.P. Petrova1

[1] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru

THERMOSETTING BINDERS FOR POLYMER COMPOSITES (review)

The properties and fields of application of polymeric binders of various classes: polyester, cyan, epoxy vinyl ester, epoxy, phenol formaldehyde, organosilicon, polyimide are considered. The relationship between the rheological properties of the binders and the technological characteristics of their processing is shown. A wide range of developed binders provides  the use of all technologies for the production of composite materials: autoclave molding using the prepreg technology, resin transfer molding (RTM), vacuum assisted resin transfer molding (VARTM), resin film infusion (RFI).

Keywords: binder, melt binder, binder solution, polyester binder, epoxy binder, phenol formaldehyde binder, binder processing technologies.

Reference List

    1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.

    2. Kablov E.N. Materialy novogo pokoleniya [New generation materials] // Zashchita i bezopasnost. 2014. №4. S. 28–29.

    3. Chursova L.V., Grebeneva T.A., Panina N.N., Tsybin A.I. Svyazuyushchiye dlya polimernykh kompozitsionnykh materialov stroitelnogo naznacheniya [Binders for polymeric composite materials for construction] // Vse materialy. Entsiklopedicheskiy spravochnik. 2015. №8. S. 13–17.

    4. Alentyev A.Yu., Yablokova M.Yu. Svyazuyushchiye dlya polimernykh kompozitsionnykh materialov [Binders for polymer composites]. M.: MGU im M.V. Lomonosova, 2010. 69 s.

    5. Mishkin S.I., Raskutin A.E., Evdokimov A.A., Gulyaev I.N. Tehnologii i osnovnye etapy stroitelstva pervogo v Rossii arochnogo mosta iz kompozicionnyh materialov [Technologies and the main stages of construction of the arch bridge first in Russia from composite materials] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2017. №6 (54). St. 05. Available at: http://www.viam-works.ru (accessed: March 06, 2019). DOI: 10.18577/2307-6046-2017-0-6-5-5.

    6. Mukhametov R.R., Petrova A.P. Svoystva epoksidnykh polimernykh svyazuyushchikh i ikh pererabotka v polimernyye kompozitsionnyye materialy [Properties of epoxy binders and their processing in polymers composition materials] // Novosti materialovedeniya. Nauka i tekhnika: elektron. nauch.-tekhnich. zhurn. 2018. №3–4 (30). St. 06. Available at: http://www.materialsnews.ru (accessed: March 06, 2019).

    7. Muhametov R.R., Petrova A.P., Ponomarenko S.A., Ahmadieva K.R., Pavlyuk B.F. Vliyanie tkanyh voloknistyh napolnitelej razlichnyh tipov na svojstva otverzhdennogo svyazuyushchego VS-2526K [Influence of woven fibrous fillers of various types on properties of cured binder VS-2526K] // Trudy VIAM: elektron. nauch.-tekhnich. zhurn. 2018. №3 (63). St. 04. Available at: http//www.viam-works.ru (accessed: March 06, 2019). DOI: 10.18577/2307-6046-2018-0-3-28-36.

    8. Muhametov R.R., Petrova A.P., Ponomarenko S.A., Dolgova E.V., Pavlyuk B.F. Svojstva svyazuyushchego EDT-69N i PKM na ego osnove [Properties of binder EDT-69N and polymer composites on its basis] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2018. №4 (64). St. 04. Available at: http//www.viam-works.ru (accessed: March 06, 2019). DOI: 10.18577/2307-6046-2018-0-4-4-4.

    9. Babin A. N. Svyazujushhie dlya polimernyh kompozicionnyh materialov novogo pokoleniya [Binding for polymeric composite materials of new generation] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №4. St. 11. Available at: http://www.viam-works.ru (accessed: March 06, 2019).

    10. Postnova M.V., Postnov V.I. Opyt razvitiya bezavtoklavnyh metodov formovaniya PKM [Development experience out-of-autoclave methods of formation PCM]// Trudy VIAM: ehlektron. nauch.-tekhnich. zhurn. 2014. №4. St. 06. Available at: http://www.viam-works.ru (accessed: March 06, 2019). DOI 10.18577/2307-6046-2014-0-4-6-6.

    11. Panina N.N., Kim M.A., Gurevich Ya.M. i dr. Svyazuyushchiye dlya bezavtoklavnogo formovaniya izdeliy iz polimernykh kompozitsionnykh materialov [Binders for non-autoclaving molding products from polymer composite materials] // Klei. Germetiki. Tekhnologii. 2013. №10. S. 18–27.

    12. Kablov E.N., Chursova L.V., Babin A.N., Mukhametov R.R., Panina N.N. Razrabotki FGUP «VIAM» v oblasti rasplavnykh svyazuyushchikh dlya polimernykh kompozitsionnykh materialov [Developments of FSUE «VIAM» in the field of melt binders for polymer composite materials] // Polimernyye materialy i tekhnologii. 2016. T. 2. №2. S. 37–42.

    13. Muhametov R.R., Ahmadieva K.R., Kim M.A., Babin A.N. Rasplavnye svyazujushhie dlya perspektivnyh metodov izgotovleniya PKM novogo pokoleniya [Melt binding for perspective methods of production of PCM of new generation] // Aviacionnye materialy i tehnologii. 2012. №S. S. 260–265.

    14. Chursova L.V., Panina N.N., Grebeneva T.A., Terekhov I.V., Donetskiy K.I. Termoreaktivnyye svyazuyushchiye i polimernyye bindery dlya polimernykh kompozitsionnykh materialov, poluchayemykh metodom vakuumnoy infuzii [Thermosetting binders and polymer binders for polymer composites obtained by vacuum infusion] // Plasticheskiye massy. 2018. №1–2. S. 57–63.

    15. Chursova L.V., Dushin M.I., Kogan D.I. i dr. Plenochnyye svyazuyushchiye dlya RFI-tekhnologii [Film Binders for RFI Technology] // Rossiyskiy khimicheskiy zhurnal. 2010. T. LIV. №1. S. 63–66.

    16. Kogan D.I., Chursova L.V., Petrova A.P. Tekhnologiya izgotovleniya PKM sposobom propitki plenochnym svyazuyushchim [Manufacturing technology PCM method of impregnation film binder] // Klei. Germetiki. Tekhnologii. 2011. №6. S. 25–29.

    17. Kogan D.I., Chursova L.V., Petrova A.P. Polimernyye kompozitsionnyye materialy, poluchennyye putem propitki plenochnym svyazuyushchim [Polymer composite materials obtained by impregnation with film binder] // Vse materialy. Entsiklopedicheskiy spravochnik. 2011. №11. S. 2–6.

    18. Petrovа A.P., Dementyevа L.A., Lukina N.F., Chursova L.V. Kleevye svjazujushhie dlja polimernyh kompozicionnyh materialov na ugle- i steklonapolniteljah [Adhesive binders for polymer composite materials based on carbon- and glass fillers] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №9. St. 11. Available at: http://www.viam-works.ru (accessed: March 06, 2019). DOI: 10.18577/2307-6046-2015-0-9-11-11.

    19. Zastrogina O.B., Shvets N.I., Postnov V.I., Serkova E.A. Fenolformaldegidnye svjazuyushhie novogo pokoleniya dlya materialov interera [Phenolformaldehyde binding new generation for interior materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 265–272.

    20. Zastrogina O.B., Shvets, N.I., Serkova E.A., Veshkin A.E. Pozharobezopasnyye materialy na osnove fenoloformaldegidnykh svyazuyushchikh [Fireproof materials based on phenol-formaldehyde binders] // Klei. Germetiki. Tekhnologii. 2017. №7. S. 22–27.

    21. Shvets N.I., Zastrogina O.B., Barbotko S.L., Aleksashin V.M. Fenolformaldegidnoye svyazuyushcheye ponizhennoy goryuchesti [Phenol-formaldehyde binder of low flammability] // Pozharovzryvobezopasnost. 2013. T. 22. S. 26–32.

    22. Minakov V.T., Shvets N.I., Zastrogina O.B., Postnov V.I., Chursova L.V., Barbot'ko S.L. Pozharobezopasnyye materialy, ne soderzhashchiye antipirenov, dlya inter'yera passazhirskikh samoletov [Fireproof materials that do not contain flame retardants for the interior of passenger aircraft] // Izvestiya Samarskogo nauchnogo tsentra Rossiyskoy akademii nauk. Spets. vyp.: Chetvert veka izyskaniy i eksperimentov po sozdaniyu unikalnykh tekhnologiy i materialov dlya aviastroyeniya UNTTS-FGUP «VIAM». 2008. S. 24–28.

    23. Davydova I.F., Kavun N.S. Stekloplastiki ‒ mnogofunkcionalnye kompozicionnye materialy [Fibreglasses ‒ multipurpose composite materials] //Aviacionnye materialy i tehnologii. 2012. №S. S. 253–260.

    24. Kitayeva N.S., Minakov V.T., Shvets N.I., Deev I.S., Babin A.N., Ponitkova E.M. 50 let laboratorii «Polimernyye svyazuyushchiye dlya nemetallicheskikh materialov i spetsialnyye zhidkosti» [50 years of the laboratory «Polymeric binders for non-metallic materials and special liquids»]. M.: VIAM, 2010. 30 s.

    25. Davydova I.F., Kablov E.N., Kavun N.S. Termostoykiye negoryuchiye poliimidnyye steklotekstolity dlya izdeliy aviatsionnoy i raketnoy tekhniki [Heat-resistant non-flammable polyimide fiberglass for aviation and rocket technology products] // Vse materialy. Entsiklopedicheskiy spravochnik. 2009. №7. S. 2–11.

    26. Davydova I.F., Kavun N.S. Poliimidnyj steklotekstolit s ponizhennoj temperaturoj otverzhdeniya [Polyimide fiberglass plastic with lower curing temperature] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №2. St. 09. Available at: http://www.viam-works.ru (accessed: March 06, 2019). DOI: 10.18577/2307-6046-2015-0-2-8-8.

    27. Gulyaev I.N., Vlasenko F.S., Zelenina I.V., Raskutin A.E. Napravleniya razvitiya termostojkih ugleplastikov na osnove poliimidnyh i geterociklicheskih polimerov [Development Directions of heat-resistant carbon–fiber–reinforced–plastics based on polimide and heterocyclic polymers] // Trudy VIAM: elektron. nauch.-tehni. zhurn. 2014. №1. St. 04. Available at: http://www.viam-works.ru (accessed: March 06, 2019). DOI: 10.18577/2307-6046-2014-0-1-4-4.

    28. Trostyanskaya E.B., Mikhaylin Yu.A., Khokhlova L.F. i dr. Ugleplastiki na osnove polimerizuyushchikhsya imidov API-2 [Carbon plastics based on polymerizing imides API-2] // Voprosy aviatsionnoy nauki i tekhniki. Ser.: Aviacionnye materialy. M.: VIAM, 1985. S. 12–19.

    29. Zharinov M.A., Shimkin A.A., Akhmadiyeva K.R., Zelenina I.V. Osobennosti i svoystva rasplavnogo poliimidnogo svyazuyushchego polimerizatsionnogo tipa [Features and properties of solvent-free PMR-type polyimide resin] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2018. №12 (72). St. 05. Available at: http://www.viam-works.ru (accessed: March 06, 2019). DOI: 10.18577/2307-6046-2018-0-12-46-53.

    30. Mukhametov R.R., Merkulova Yu.I., Chursova L.V. Termoreaktivnyye polimernyye svyazuyushchiye s prognoziruyemym urovnem reologicheskikh i deformatsionnykh svoystv // Klei. Germetiki. Tekhnologii. 2012. №5. S. 19–21.

    31. Merkulova Yu.I., Muhametov R.R., Dolgova E.V., Ahmadieva K.R. Policianuratnoe svyazuyushhee dlya polucheniya kompozitov propitkoj pod davleniem [Polycyanurates binding for composites production by impregnation under pressure] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №11 (47). St. 05. Available at: http://www.viam-works.ru (accessed: March 06, 2019). DOI: 10.18577/2307-6046-2016-0-11-5-5.

    32. Zheleznyak V.G., Chursova L.V., Merkulova Yu.I., Dolgova E.V. Svyazuyushchiye dlya PKM s povyshennoy vyazkostyu razrusheniya [Binders for PCM with increased fracture toughness] // Klei. Germetiki. Tekhnologii. 2015. №1. S. 26–28.

    33. Zheleznyak V.G., Chursova L.V. Modifikaciya svyazujushhih i matric na ih osnove s celyu povysheniya vyazkosti razrusheniya [Modification of binders and matrixes based on them to increase fracture toughness] // Aviacionnye materialy i tehnologii. 2014. №1. S. 47–50. DOI: 10.18577/2071-9140-2014-0-1-47-50.

Full version

DOI: 10.18577/2071-9140-2019-0-3-59-66

UDC: 621.357.74

Pages: 59-66

S.S. Vinogradov1, A.A. Nikiforov1, L.I. Zakirova1

[1] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru

CADMIUM REPLACEMENT. STAGE 2 – FINAL. GALVANIC THERMAL COATING OF  ZINC–TIN SYSTEM – REAL ALTERNATIVE TO CADMIUM PLATING

In VIAM the galvanic thermal coating of zinc–tin system possessing high protective ability has been developed and patented: with cut to steel basis for more than 6000 h in the salt spray chamber, this corresponds to protective ability of cadmium coating. Forming of galvanic thermal coating of the zinc–tin system is as follows: consecutive electrochemical plating of zinc and tin layers, thermal processing at temperature not higher than 200°С and such duration at which there is no «germination» of hypereutectic tin-zinc alloy through tin layers.

Keywords: galvanic thermal coating, cadmium plating, level-by-level plating, thermal processing, alloy tin-zinc, protective ability, electrochemical researches, adhesion, mechanical properties of carbon steels.

Reference List

    1. Kablov E.N. Korroziya ili zhizn [Corrosion or life] // Nauka i zhizn. 2012. №11. S. 16–21.

    2. Kablov E.N., Startsev O.V. Fundamentalnye i prikladnye issledovaniya korrozii i stareniya materialov v klimaticheskih usloviyah (obzor) [The basic and applied research in the field of corrosion and ageing of materials in natural environments (review)] // Aviacionnye materialy i tehnologii. 2015. №4 (37). S. 38–52. DOI: 10.18577/2071-9140-2015-0-4-38-52.

    3. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.

    4. GN 2.2.5.3532–18. Predelno dopustimyye kontsentratsii (PDK) vrednykh veshchestv v vozdukhe rabochey zony: utv. Postanovleniyem Glavnogo gosudarstvennogo sanitarnogo vracha Rossiyskoy Federatsii 13.02.2018: vvod. v dejstvie 03.05.2018.

    5. Glushko Ya.M. Vrednye neorganicheskiye soyedineniya v promyshlennykh stochnykh vodakh: spravochnik [Harmful inorganic compounds in industrial wastewater: guide]. L.: Khimiya, 1979. 160 s.

    6. Bondar V.V., Grinina V.V., Pavlov V.N. Elektroosazhdeniye dvoynykh splavov [Electrodeposition of double alloys] // Itogi nauki i tekhniki. Elektrokhimiya. M.: VINITI, T. 16. 1980. 331 s.

    7. Galvanicheskiye pokrytiya v mashinostroyenii: spravochnik v 2 t. / pod red. M.A. Shlugera, L.D. Toka [Electroplated coatings in mechanical engineering: reference book in 2 vol. / ed. M.A. Shluger, L.D. Tok]. M.: Mashinostroyeniye, 1985. T. 1. 240 s.

    8. Vyacheslavov P.M. Elektroliticheskoye osazhdeniye splavov [Electrolytic deposition of alloys]. L.: Mashinostroyeniye, 1986. 112 s.

    9. Azhogin F.F., Belenkiy M.A., Gal I.E. i dr. Galvanotekhnika [Electroplating]. M.: Metallurgiya, 1987. S. 484–485.

    10. Corrosion resistant coating system and method: pat. US 6613452; filed 16.01.01; publ. 02.09.03.

    11. Sposob naneseniya kombinirovannogo zashchitnogo pokrytiya na stalnye detali: pat. 2427671 Ros. Federatsiya [The method of applying a combined protective coating on steel parts: pat. 2427671 Rus. Federation]; zayavl. 18.08.10. opubl. 27.08.11.

    12. Sposob polucheniya pokrytiya dlya zashchity ot korrozii stalnykh detaley: pat. 2177055 Ros. Federatsiya [A method of obtaining a coating for corrosion protection of steel parts: pat. 2177055 Rus. Federation]; zayavl. 30.03.00; opubl. 20.12.01.

    13. Vinogradov S.S., Nikiforov A.A., Balahonov S.V. Zamena kadmiya. Etap 1. Povyshenie zashhitnoj sposobnosti cinkovyh pokrytij: termoimmersionnoe i modificirovannoe pokrytiya [Cadmium replacement. Part 1. Improving of protective property of zinc coatings: thermo-immersed and modified coatings] // Aviacionnye materialy i tehnologii. 2015. №4 (37). S. 53–60. DOI: 10.18577/2071-9140-2015-0-4-53-60.

    14. Sposob polucheniya zashchitnogo pokrytiya: pat. 2606364 Ros. Federatsiya [A method of obtaining a protective coating: pat. 2606364 Rus. Federation]; zayavl. 15.10.15. opubl. 10.01.17.

    15. Kablov E.N., Nikiforov A.A., Demin S.A., Chesnokov D.V., Vinogradov S.S. Perspektivnyye pokrytiya dlya zashchity ot korrozii uglerodistykh staley [Promising coatings for corrosion protection of carbon steels] // Stal. 2016. №6. S. 70–81.

    16. Vinogradov S.S., Nikiforov A.A., Demin S.A. Puti resheniya problemy zameny kadmiyevogo pokrytiya [Ways to solve the problem of cadmium coating replacement] // Galvanotekhnika i obrabotka poverkhnosti. 2018. T. 26. №2. S. 13–25.

    17. Vinogradov S.S., Nikiforov A.A., Demin S.A., Chesnokov D.V. Zashchita ot korrozii uglerodistykh stalej [Protection against corrosion of carbon steel] // Aviacionnye materialy i tehnologii. 2017. №S. S. 242–263. DOI: 10.18577/2071-9140-2017-0-S-242-263.

    18. GOST 9.005–72. Dopustimyye i nedopustimyye kontakty metallov. Obshchiye trebovaniya [State Standard 9.005–72. Admissible and unacceptable metal contacts. General requirements]. M.: Izd-vo standartov, 1972. 27 s.

    19. Diagrammy sostoyaniya dvoynykh metallicheskikh sistem: spravochnik v 3 t. / pod obshch. red. N.P. Lyakisheva [State diagrams of double metal systems: guide in 3 vol. / ed. N.P. Lyakishev]. M.: Mashinostroyeniye, 2000. T. 3, kn. 2. S. 340–341.

    20. Kovenskiy I.M. Otzhig elektroosazhdennykh metallov i splavov [Annealing of electrodeposited metals and alloys]. Tyumen: TyumGNGU, 1995. 92 s.

Full version

DOI: 10.18577/2071-9140-2019-0-3-67-74

UDC: 621.78

Pages: 67-74

D.P. Farafonov1, N.E. Leshchev1, A.N. Afanasiev-Khodykin1, N.I. Artemenko1

[1] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru

ABRASIVE WEAR-RESISTANT SEAL MATERIALS OF THE GAS TURBINE ENGINE FLOW SECTION

The paper provides the main results of the works performed by VIAM Federal State Unitary Enterprise devoted to the improvement of wear resistance of seals in gas turbine engines. There are examined the tribotechnical characteristics of wear-resistant and composite abrasive materials and coatings obtained by different methods, such as: detonation spraying, electrosedimentation, vacuum soldering. Some abrasive and wear-resistant materials the basis of which represents a metal matrix with the particles of hard high-melting compounds dispersed in it are developed.

Keywords: abrasive wear-resistant material, blades tips, abrasive coatings, sealing materials, durability, gas-turbine engine.

Reference List

    1. Inozemtsev A.A., Sandratskiy V.L. Gazoturbinnyye dvigateli [Gas turbine engines]. Perm: Aviadvigatel, 2006. S. 278–280.

    2. Greshta V., Tkach D., Sotnikov Ye. et al. Studing and designing improved coatings for labyrinth seals of gas-turbine engine turbines // Eastern-European Journal of Enterprise Technologies. 2018. Vol. 4/12 (94). P. 56–63.

    3. Farafonov D.P., Migunov V.P., Sarayev A.A., Leshchev N.E. Istirayemost i erozionnaya stoykost uplotnitelnykh materialov protochnoy chasti GTD [Abradability and erosion resistance of seals in turbine engine air-gas channel] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2018. №8 (68). St. 07. Available at: http://www.viam-works.ru (accessed: March 14, 2019). DOI: 10.18577/2307-6046-2018-0-8-70-80.

    4. Wilson S. Overview of Sulzer Metco compressor and turbine abradable technology // 8th International Charles Parsons Turbine Conference. 2011. Available at: http://www.iom3.org/sites/default/files/iom3-corp/wed%200940%20s%20Wilso... (accessed: March 14, 2019).

    5. Simms N.J., Norton J.F., McColvin G. Performance of candidate gas turbine abradeable seal materials in high temperature combustion atmospheres // Materials and Corrosion. 2005. Vol. 56. P. 765–777.

    6. Bill R.C., Ludwig L.P. Wear of seal materials used in aircraft // Wear. 1980. Vol. 59. P. 165–189.

    7. Migunov V.P. Materialy dlya uplotneniya gazovogo kontura v kompressore i turbine [Materials for sealing the gas circuit in the compressor and the turbine] // Aviacionnye materialy i tehnologii. 2003. №1. S. 165–169.

    8. Afanasev-Khodykin A.N., Rylnikov V.S., Farafonov D.P. Tekhnologiya pajki poristo-voloknistogo materiala iz splava tipa «fekhral» dlya uplotneniya protochnoj chasti GTD [Technology soldering porous fibrous material of the alloy of the «fehral» to seal the flow part of GTE] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №1. St. 02. Available at: http://www.viam-works.ru (accessed: March 14, 2019). DOI: 10.18577/2307-6046-2014-0-1-2-2.

    9. Smarsly W., Zheng N., Buchheim C.S. et al. Advanced High Temperature Turbine Seals Materials and Designs // Material Science Forum. 2005. Vol. 492–493. P. 21–26.

    10. Davenport J.R., Mendez-Garcia L., Purkayastha S. et al. Material needs for turbine sealing at high temperature // Materials Science and Technology. 2014. Vol. 30. No 15. P. 1877–1883.

    11. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.

    12. Kablov E.N. Materialy novogo pokoleniya – osnova innovatsiy, tekhnologicheskogo liderstva i natsionalnoy bezopasnosti Rossii [Kablov E.N. Materials of the new generation - the basis of innovation, technological leadership and national security of Russia] // Intellekt i tekhnologii. 2016. №2 (14). S. 16–21.

    13. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period to 2030] // Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.

    14. Farafonov D.P., Bazyleva O.A., Rogalev A.M. Splavy dlya uprochneniya bandazhnyh polok rabochih lopatok GTD [Alloys for blade shroud hardening] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №9. St. 07. Available at: http://www.viam-works.ru (accessed: March 15, 2019). DOI: 10.18577/2307-6046-2016-0-9-7-7.

    15. Coating forming method and coating forming material, and abrasive coating forming sheet: pat. 7063250 B2 US; field 13.05.04; publ. 20.07.06.

    16. Abrasive coating and manufacture and use methods: pat. 10018056 B2 US; field 25.06.2015; publ. 10.07.18.

    17. Wear-resistant coating and method for applying it: pat. 6811898 B2 US; field 01.04.03; publ. 2.11.04.

    18. Kablov E.N., Muboyadzhyan S.A. Erozionnostoykiye pokrytiya dlya lopatok kompressora gazoturbinnykh dvigateley [Erosion-resistant coatings for compressor blades for gas turbine engines] // Elektrometallurgiya. 2016. №10. S. 23–38.

    19. Kablov E.N., Muboyadzhyan S.A., Budinovskiy S.A., Egorova L.N., Lutsenko A.N., Galoyan A.G. Zashchitnyye i uprochnyayushchiye pokrytiya lopatok i detaley GTD [Protective and hardening coatings of blades and parts of the CCD] // 75 let. Aviatsionnyye materialy. M.: VIAM, 2007. S. 107–124.

    20. Aleksandrov D.A., Artemenko N.I. Iznosostojkie pokrytiya dlya zashhity detalej treniya sovremennyh GTD [Wear-resistant coatings to protect friction parts of modern gas turbine engines] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №10. St. 06. Available at: http://www.viam-works.ru (accessed: March 15, 2019). DOI: 10.18577/2307-6046-2016-0-10-6-6.

Full version

DOI: 10.18577/2071-9140-2019-0-3-75-82

UDC: 669.017

Pages: 75-82

S.P. Konokotin1, R.M. Nazarkin1

[1] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru

THЕ TRAVELLING MAGNETIC FIELD OF BIPOLAR ELECTROMAGNETIC INDUCTOR AND ITS INFLUENCE ON THE PROPERTIES OF Cr- AND Ni-BASED POLYCRYSTALLINE ALLOYS. Part 2

For the increase of physical and mechanical properties of the Ni-based alloys by technique of equiaxial solidification in the traveling magnetic field, the design of the bipolar cylindrical electromagnetic inductor is studied. The application of the improved design of electromagnetic inductor is provided at the solidification of alloys: change of alloy microstructure, formation of directional crystallographic structure in the castings, change of phase composition and increase of heat resistance at 1250°C.

Keywords: bipolar electromagnetic inductor, traveling magnetic field, Cr-based alloys, Ni-ased alloys, alloy solidification, crystallographic texture, x-ray diffraction analysis, mechanical properties.

Reference List

    1. Kablov E.N., Petrushin N.V., Parfenovich P.I. Konstruirovaniye liteynykh zharoprochnykh nikelevykh splavov s polikristallicheskoy strukturoy [Design of heat-resistant nickel alloys with a polycrystalline structure] // Metallovedeniye i termicheskaya obrabotka metallov. 2018. №2 (752). S. 47–55.

    2. Bazyleva O.A., Arginbayeva E.G., Lutskaya S.A. Metody povysheniya korrozionnoy stoykosti zharoprochnykh nikelevykh splavov (obzor) [Ways of increasing corrosion resistance of superalloys (review)] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2018. №4. St. 01. Available at: http://www.viam-works.ru (accessed: September 03, 2018). DOI: 10.18577/2307-6046-2018-0-4-3-8.

    3. Wang J., Qian J., Zhang X., Wang Y. Research status and progress of NiAl based alloys as high temperature structure materials // Rare Metals. 2011. Vol. 30. Suppl. 1. P. 422–426.

    4. Petrushin N.V., Svetlov I.L., Ospennikova O.G. Liteynyye zharoprochnyye nikelevyye splavy [Heat-resistant foundry nickel alloys] // Vse materialy. Entsiklopedicheskiy spravochnik. 2012. №6. S. 16–21.

    5. Sims C.T., Stoloff N.S., Hagel W.C. Superalloys II: High-Temperature Materials for Aerospace and Industrial Power. N.-Y.: John Wiley & Sons, 1987. 640 p.

    6. Kablov E.N., Petrushin N.V., Elyutin E.S. Monokristallicheskiye zharoprochnyye splavy dlya gazoturbinnykh dvigateley [Monocrystalline heat-resistant alloys for gas turbine engines] // Vestnik MGTU im. N.E. Baumana. Ser.: Mashinostroyeniye. 2011. №SP2. S. 38–52.

    7. Kablov E.N., Ospennikova O.G., Svetlov I.L. Vysokoeffektivnoe ohlazhdenie lopatok goryachego trakta GTD [Highly efficient cooling of GTE hot section blades] // Aviacionnye materialy i tehnologii. 2017. №2 (47). S. 3–14. DOI: 10.18577/2071-9140-2017-0-2-3-14.

    8. Grinberg B.A., Ivanov M.A. Intermetallidy Ni3Al i TiAl: mikrostruktura, deformatsionnoye povedeniye [Intermetallides Ni3Al and TiAl: microstructure, deformation behavior]. Ekaterinburg: Izd-vo UrO RAN, 2002. 360 s.

    9. Povarova K.B., Drozdov A.A., Bazyleva O.A., Morozov A.E., Antonova A.V., Bondarenko Yu.A., Bulakhtina M.A., Ashmarin A.A., Arginbayeva E.G., Aladin N.A. Konstruktsionnyye zharostoykiye (b-NiAl+γ′-Ni3Al) splavy sistemy Ni–Al–Co. I. Osobennosti kristallizatsii i struktury splavov [Structural heat-resistant (β-NiAl+γ′-Ni3Al) alloys of the Ni–Al–Co system. I. Features of crystallization and structure of alloys] // Metally. 2017. №5. S. 20–30.

    10. Povarova K.B., Drozdov A.A., Bazyleva O.A., Morozov A.Ye., Antonova A.V., Arginbayeva E.G., Aladin N.A., Sirotinkin V.P. Konstruktsionnyye zharostoykiye (b-NiAl+γ′-Ni3Al) splavy sistemy Ni–Al–Co. II. Osobennosti kristallizatsii i struktury splavov [Structural heat-resistant (β-NiAl+γ′-Ni3Al) alloys of the Ni – Al – Co system. II. Features of crystallization and alloy structure] // Metally. 2017. №5. S. 31–36.

    11. Li H.T., Wang Q., Wang K. et al. Improvement of compressive strength and ductility in NiAl based eutectic alloy by uniform high magnetic field treatment // Intermetallics. 2011. Vol. 19. Issue 2. P. 187–190.

    12. Nikrityuk P.A., Eckert K., Grundmann R. Electromagnetically Forced Swirling Flow During Solidification of a Binary Metal alloy // Journal of Computational and Applied Mechanics. 2004. Vol. 5. No. 2. P. 337–352.

    13. Verte L.A. MGD-tekhnologiya v proizvodstve chernykh metallov [MHD technology in the production of ferrous metals]. M.: Metallurgiya, 1990. 119 s.

    14. Samoylov A.I., Konokotin S.P., Roshchina I.N. i dr. Povysheniye plastichnosti materialov kristallizatsiyey v elektromagnitnom pole [Increasing the ductility of materials by crystallization in an electromagnetic field] // Aviacionye materialy i tehnologii. 2008. Vyp. 1. S. 32–37.

    15. Bolkhovitov N.F. Metallovedeniye i termicheskaya obrabotka. M.: Mashgiz, 1961. S. 17.

    16. Mneyan M.G. Novyye professii magnita [Metal science and heat treatment]. M.: Prosveshcheniye, 1985. S. 28–35.

    17. Konokotin S.P., Moiseyeva N.S. Vliyaniye metoda kristallizatsii na strukturu splava sistemy Ni–Al posle vysokotemperaturnogo nagreva [The influence of the crystallization method on the structure of the alloy of the Ni – Al system after high-temperature heating] // Metallurgiya mashinostroyeniya. 2013. №4. S. 27–31.

    18. Konokotin S.P., Moiseeva N.S. Povyshenie fiziko-mehanicheskih svojstv splavov na osnove hroma i sistemy Ni–Al, sklonnyh k hladnolomkosti, metodom ravnoosnoj kristallizacii v elektromagnitnom pole [An increase of physical and mechanical properties of Cr-based and Ni–Al alloys by using the equiaxed crystallization in electromagnetic field] // Aviacionnye materialy i tehnologii. 2015. №3 (36). S. 15–26. DOI: 10.18577/2071-9140-2015-0-3-15-26.

    19. Nazarkin R.M., Konokotin S.P. Vliyaniye obrabotki elektromagnitnym polem pri kristallizatsii na mekhanicheskiye svoystva splavov sistem Ni–Al i Co–Cr–Al–Ni [Influence of electro-magnetic field treatment at the solidification process on mechanical properties of Ni–Al and Co–Cr–Al–Ni alloys] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2017. №5 (53). St. 10. Available at: http://www.viam-works.ru (accessed: September 03, 2018). DOI: 10.18577/2307-6046-2017-0-5-10-10.

Full version

DOI: 10.18577/2071-9140-2019-0-3-83-88

UDC: 620.179

Pages: 83-88

A.S. Boychuk1, I.A. Dikov1, A.S. Generalov1

[1] Federal state unitary enterprise «All-Russian scientific research institute of aviation materials»

THE INCREASE OF SENSITIVITY AND RESOLUTION OF FRP SOLID SAMPLES NONDESTRUCTIVE ULTRASONIC TESTING USING THE ULTRASONIC PHASED ARRAY 

Wide scatter of the defined values is observed during the testing of Fibre-Reinforced Plastics (FRP) solid-cast samples for definition of their physical and mechanical properties. One of the factors affecting this scatter is the presence of internal defects in the test samples. Nowadays the nondestructive inspection sensitivity of FRP solid-cast sample structures which equals to 5 mm diameter flat bottom hole detection is insufficient for detection of defects affecting the mechanical test results. This article gives the test results and shows that it is possible to increase the sensitivity and resolution of CFRP and GFRP solid-cast samples ultrasonic testing by using ultrasonic beam focusing,  increasing the number of elements in phased array transducer in electronic scanning group and decreasing scanning pitch.

Keywords: polymer composite materials, nondestructive testing, ultrasonic testing, phased array, sensitivity, resolution.

Reference List

    1. Kablov E.N. Iz chego sdelat budushcheye? Materialy novogo pokoleniya, tekhnologii ikh sozdaniya i pererabotki – osnova innovatsiy [What to make the future from? Materials of the new generation, technologies of their creation and processing - the basis of innovation] // Krylya Rodiny. 2016. №5. S. 8–18.
    2. Savin S.P. Primeneniye sovremennykh polimernykh kompozitsionnykh materialov v konstruktsii planera samoletov semeystva MS-21 [The use of modern polymer composite materials in the construction of a glider of airplanes of the MS-21 family] // Izvestiya Samarskogo nauchnogo tsentra Rossiyskoy akademii nauk. 2012. T. 14. №4 (2). S. 686–693.
    3. Timoshkov P.N., Platonov A.A., Hrulkov A.V. Propitka plenochnym svyazuyushhim (RFI) kak perspektivnaya bezavtoklavnaya tehnologiya polucheniya izdelij iz PKM [Film resin infusion as an advanced method for out-of-autoclave processing of polymer composites] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №5. St. 09. Available at: http://www.viam-works.ru (accessed: February 05, 2019). DOI: 10.18577/2307-6046-2015-0-5-9-9.
    4. Mishkin S.I., Raskutin A.E., Evdokimov A.A., Gulyaev I.N. Tehnologii i osnovnye etapy stroitelstva pervogo v Rossii arochnogo mosta iz kompozicionnyh materialov [Technologies and the main stages of construction of the arch bridge first in Russia from composite materials] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2017. №6 (54). St. 05. Available at: http://www.viam-works.ru (accessed: February 01, 2019). DOI: 10.18577/2307-6046-2017-0-6-5-5.
    5. Goncharov V.A., Raskutin A.E. Kompyuternoe modelirovanie processa infuzii pri izgotovlenii kompozitnogo arochnogo elementa [Computer modeling of the infusion process in the manufacture of composite arched element] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №7. St. 11. Available at: http://www.viam-works.ru (accessed: February 01, 2019). DOI: 10.18577/2307-6046-2015-0-7-11-11.
    6. Veshkin E.A. Osobennosti bezavtoklavnogo formovaniya nizkoporistykh PKM [Features of out-of-autoclave forming of poor-porous PCM] // Trudy VIAM elektron. nauch.-tehnich. zhurn. 2016. №2. St. 07. Available at: http://www.viam-works.ru (accessed: February 05, 2019). DOI 10.1857/2307-6046-2016-0-2-7-7.
    7. Kablov E.N., Chursova L.V., Babin A.N., Mukhametov R.R., Panina N.N. Razrabotki FGUP «VIAM» v oblasti rasplavnykh svyazuyushchikh dlya polimernykh kompozitsionnykh materialov [Developments of FSUE «VIAM» in the field of melt binders for polymer composite materials] // Polimernyye materialy i tekhnologii. 2016. T. 2. №2. S. 37–42.
    8. Raskutin A.E. Rossiiskie polimernye kompozitsionnye materialy novogo pokoleniia, ikh osvoenie i vnedrenie v perspektivnykh razrabatyvaemykh konstruktsiiakh [Russian polymer composite materials of new generation, their exploitation and implementation in advanced developed constructions] // Aviacionnye materialy i tehnologii. 2017. №S. S. 349–367. DOI: 10.18577/2071-9140-2017-0-S-349-367.
    9. Boychuk A.S., Generalov A.S., Dikov I.A. Kontrol detaley i konstruktsiy iz polimernykh kompozitsionnykh materialov s primeneniyem tekhnologii ultrazvukovykh fazirovannykh reshetok [FRP parts and structures testing by phased array technique] // Aviacionnyye materialy i tehnologii. 2017. №1 (46). S. 45–50. DOI: 10.18577/2071-9140-2017-0-1-45-50.
    10. Boychuk A.S., Generalov A.S., Dalin M.A., Stepanov A.V. Nerazrushayushchiy kontrol tekhnologicheskikh narusheniy sploshnosti T-obraznoy zony integralnoy konstruktsii iz PKM s ispolzovaniyem ultrazvukovykh fazirovannykh reshetok [Non-destructive testing of technological discontinuities of the T-shaped zone of the integral structure made of PCM using phased ultrasound arrays] // Vse materialy. Entsiklopedicheskiy spravochnik. 2012. №10. S. 38–44.
    11. Boychuk A.S., Generalov A.S., Dalin M.A., Dikov I.A. Kontrol monolitnykh detaley i konstruktsiy aviatsionnoy tekhniki, izgotavlivayemykh iz PKM, ultrazvukovym metodom nerazrushayushchego kontrolya s ispol'zovaniyem fazirovannykh reshetok [Control of monolithic parts and structures of aviation equipment made of PCM using an ultrasonic method of non-destructive testing using phased arrays] // X Vseros. konf. TestMat «Osnovnyye tendentsii, napravleniya i perspektivy razvitiya metodov nerazrushayushchego kontrolya v aerokosmicheskoy otrasli». M.: VIAM, 2018. S. 18–31. Available at: https://conf.viam.ru/sites/default/files/uploads/proceedings/1063.pdf (accessed: August 21, 2018).
    12. Schadow F., Brackrock D., Gaal M., Heckel T. Ultrasonic Inspection and Data Analysis of Glass- and Carbon-Fibre-Reinforced Plastics // 3rd International Symposium on Fatigue Design and Material Defects, FDMD-2017. (September 19–22, 2017, Lecco, Italy). 2017. P. 299–306. Available at: http://www.sciencedirect.com/science/article/pii/S2452321617304481 (accessed: October 17, 2018).
    13. Hsu D.K., Kommareddy V., Barnard D.J. et al. Aerospace NDT using piezoceramic air-coupled transducers // WCNDT. 2004. Available at: http://pdfs.semanticscholar.org/5a74/6552355e7ad839 dbe78554a07257cf5a356b.pdf (accessed: November 01, 2018).
    14. Grager J., Kotschate D., Gamper J. et al. Advances in air-coupled ultrasonic testing combining an optical microphone with novel transmitter concepts // 12th European conference on Non-Destructive Testing, At Gothenburg, Sweden 2018 Available at: http://www.researchgate.net/publication /325711243_Advances_in_aircoupled_ultrasonic_testing_combining_an_optical_microphone_with_novel_transmitter_concepts (accessed: December 04, 2018).
    15. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
    16. Advances in Phased Array Ultrasonic Technology Applications // Olympus NDT, 2007. Available at: http://www.olympus-ims.com/en/books/pa/pa-advances/ (accessed: January 24, 2019).

Full version

DOI: 10.18577/2071-9140-2019-0-3-89-94

UDC: 579.8

Pages: 89-94

A.A. Krivushina1, T.V. Bobyreva1, T.V. Yakovenko1, E.V. Nikolaev1

[1] ALL-RUSSIAN SCIENTIFIC RESEARCH INSTITUTE OF AVIATION MATERIALS, admin@viam.ru

METHODS OF MICROORGANISMS-DESTRUCTORS STORAGE IN FSUE «VIAM» COLLECTION (review)

Cultures of microorganisms-destructors are used for testing the microbiological resistance of materials and products. The collection in the laboratory of FSUE «VIAM» numbers over a hundred of strains of microorganisms collected from various climatic zones. Various methods of microorganism culture storage are used to preserve the collection. Short-term methods include subculturing and storage on samples of biodegradable materials. Long-term methods include the method of cryogenic freezing and lyophilization. All four methods of storage are used to preserve the viability and the necessary physiological properties of strains of microorganisms-destructors.

Keywords: biodeterioration, microorganisms-destructors, microbiological resistance, storage methods, subculturing, freezing, lyophilization

Reference List

    1. Buznik V.M., Kablov E.N. Arkticheskoye materialovedeniye [Arctic material science]. Tomsk: Tomskiy gos. un-t, 2018. Vyp. 3. 44 s.
    2. Polyakova A.V., Krivushina A.A., Goryashnik Yu.S., Yakovenko T.V. Ispytaniya na mikrobiologicheskuyu stojkost v usloviyah teplogo i vlazhnogo klimata [Microbiological resistance tests under conditions of warm and damp climate] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №7. St. 06. Available at: http://www.viam-works.ru (accessed: February 25, 2019).
    3. Polyakova A.V., Krivushina A.A., Goryashnik Yu.S., Buharev G.M. Ispytaniya na mikrobiologicheskuyu stojkost v naturnyh usloviyah razlichnyh klimaticheskih zon [Microbiological resistance tests under nature conditions in variety of climatiс zones] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №4. St. 11. Available at: http://www.viam-works.ru (accessed: February 25, 2019). DOI: 10.18577/2307-6046-2016-0-4-11-11.
    4. Kablov E.N. Klyuchevaya problema – materialy [The key problem is materials] // Tendentsii i oriyentiry innovatsionnogo razvitiya Rossii. M.: VIAM, 2015. S. 458–464.
    5. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
    6. Pokhilenko V.D., Baranov A.M., Detushev K.V. Metody dlitelnogo khraneniya kollektsionnykh mikroorganizmov i tendentsii razvitiya [Methods of long-term storage of collection microorganisms and development trends] // Izvestiya vysshikh uchebnykh zavedeniy. Povolzhskiy region. Ser.: Meditsinskiye nauki. 2009. №4 (12). S. 99–121.
    7. Krivushina A.A., Chekunova L.N., Mokeyeva V.L. Morfologicheskiye osobennosti shtammov «kerosinovogo» griba Hormoconis resinae pri roste v aviatsionnom toplive i na pitatel'nykh sredakh [Morphological features of the «kerosene» fungus Hormoconis resinae with growth in aviation fuel and in nutrient media] // Mikologiya i fitopatologiya. 2019. №1. S. 23–32.
    8. GOST 9.048–89. Edinaya sistema zashchity ot korrozii i stareniya (ESZKS). Izdeliya tekhnicheskiye. Metody laboratornykh ispytaniy na stoykost k vozdeystviyu plesnevykh gribov [State Standard 9.048–89. Uniform system of protection against corrosion and aging (ESZKS). Technical products. Laboratory test methods for resistance to mold fungi]. M.: Izd-vo standartov, 1994. 23 s.
    9. ASTM G21-15. Standard Practice for Determining Resistance of Synthetic Polymeric Materials to Fungi. West Conshohocken (United States): ASTM International, 2015. 6 p.
    10. Gerna R. Khraneniye mikroorganizmov [Storage of microorganisms] // Metody obshchey bakteriologii. Per. s angl. M.: Mir, 1983. S. 512–534.
    11. Donev T. Methods for Conservation of Industrial Microorganisms. Sofia, 2001. 93 p.
    12. GOST 9.023–74. Edinaya sistema zashchity ot korrozii i stareniya (ESZKS). Topliva neftyanyye. Metod laboratornykh ispytaniy biostoykosti topliv, zashchishchennykh protivomikrobnymi prisadkami [State Standard 9.023–74. Uniform system of protection against corrosion and aging (ESZKS). Fuel oil. Laboratory test method for biostability of fuels protected by antimicrobial additives]. M.: Izd-vo standartov, 1994. 9 s.
    13. Krivushina A.A. Mikromitsety v aviatsionnom toplive: avtoref. dis. … kand. biol. nauk [Micromycetes in aviation fuel: thesis, Cand. Sc. (Bio.)]. M.: MGU im. M.V. Lomonosova, 2012. 24 s.
    14. Krivushina A.A., Goryashnik Yu.S. Sposoby zashchity materialov i izdeliy ot mikrobiologicheskogo porazheniya (obzor) [Ways of protection of materials and products from microbiological damage (review)] // Aviacionnye materialy i tehnologii. 2017. №2 (47). S. 80–86. DOI: 10.18577/2071-9140-2017-0-2-80-86.
    15. Chaikun A.M., Naumov I.S., Alifanov E.V. Rezinovye uplotnitelnye materialy (obzor) [Rubber sealing materials (review)] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2017. №1 (49). St. 12. Available at: http //www.viam-works.ru (accessed: February 25, 2019). DOI: 10.18577/2307-6046-2017-0-1-12-12.
    16. Heckly R.J. Preservation of microorganisms // Advances in applied microbiology. San Diego: Academic Press, 1978. Vol. 24. P. 1–53.
    17. Ozerskaya S.M. Griby v kollektsiyakh kultur: fundamentalnyye i prikladnyye aspekty: avtoref. dis. … dokt. biol. nauk [Mushrooms in collections of cultures: fundamental and applied aspects: thesis, Dr. Sc. (Bio.)]. M.: MGU im. M.V. Lomonosova, 2012. 50 s.
    18. Vazhinskaya I.S., Kuptsov V.N., Kolomiyets E.I. i dr. Kriokonservatsiya kak effektivnyy sposob khraneniya fitopatogennykh gribov [Cryopreservation as an effective way to store phytopathogenic fungi] // Izvestiya Natsionalnoy akademii nauk Belarusi. Ser. biol. nauk. 2011. №4. S. 57–62.
    19. Lapage S.P., Shelton J.E., Mitchell Т.G., Mackenzie A.R. Culture collections and the preservation of bacteria // Methods in microbiology. London Academic Press. 1970. Vol. 3А. Р. 135–228.
    20. Malik K.A., Claus D. Bacterial culture collection: Their importance to biotechnology and microbiology // Biotechnology and Genetic engineering reviews. 1987. Vol. 5. P. 137–197.
    21. American type culture collection methods: 1. Laboratory manual on preservation. Freezing and freeze-drying as applied to algae, bacteria, fungi and protozoa. Rockville (Maryland): ATCC. 1980. 51 p.
    22. Uzunova-Doneva T., Donev T. Аnabiosis and conservation of microorganisms // Journal of Culture Collections. 2004. 2005. Vol. 4. Р. 17–28.
    23. Morgan C.A., Herman N., White P.A., Vesey G. Preservation of micro-organisms by drying: a review // Journal of Microbiological Methods. 2006. Vol. 66. No. 2. P. 183–193.
    24. Belyaev A.A., Bespalova E.E. Vybor tekhnologicheskikh rezhimov sushki voloknistykh penomaterialov [Choice of technological modes of drying fibrous foam materials] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2017. №6 (54). St. 08. Available at: http://www.viam-works.ru (accessed: February 25, 2019). DOI: 10.18577/2307-6046-2017-0-6-8-8.

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